Ontology highlight
ABSTRACT:
SUBMITTER: Solis Munana P
PROVIDER: S-EPMC7159596 | biostudies-literature | 2018 Dec
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20181115 50
Dissipative self-assembly processes in nature rely on chemical fuels that activate proteins for assembly through the formation of a noncovalent complex. The catalytic activity of the assemblies causes fuel degradation, resulting in the formation of an assembly in a high-energy, out-of-equilibrium state. Herein, we apply this concept to a synthetic system and demonstrate that a substrate can induce the formation of vesicular assemblies, which act as cooperative catalysts for cleavage of the same ...[more]