Dataset Information

Enhanced Power Conversion Efficiency of Dye-Sensitized Solar Cells by Band Edge Shift of TiO₂ Photoanode.

ABSTRACT: By simple soaking titanium dioxide (TiO₂) films in an aqueous Na₂S solution, we could prepare surface-modified photoanodes for application to dye-sensitized solar cells (DSSCs). An improvement in both the open-circuit voltage (V_oc) and the fill factor (FF) was observed in the DSSC with the 5 min-soaked photoanode, compared with those of the control cell without any modification. The UV-visible absorbance spectra, UPS valence band spectra, and dark current measurements revealed that the Na₂S modification led to the formation of anions on the TiO₂ surface, and thereby shifted the conduction band edge of TiO₂ in the negative (upward) direction, inducing an increase of 29 mV in the V_oc. It was also found that the increased FF value in the surface-treated device was attributed to an elevation in the shunt resistance.

SUBMITTER: Sung HK

PROVIDER: S-EPMC7181208 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature

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Publications

Enhanced Power Conversion Efficiency of Dye-Sensitized Solar Cells by Band Edge Shift of TiO2 Photoanode.

Sung Hye Kyeong HK Lee Yeonju Y Kim Wook Hyun WH Lee Sang-Ju SJ Sung Shi-Joon SJ Kim Dae-Hwan DH Han Yoon Soo YS

Molecules (Basel, Switzerland) 20200326 7

By simple soaking titanium dioxide (TiO2) films in an aqueous Na2S solution, we could prepare surface-modified photoanodes for application to dye-sensitized solar cells (DSSCs). An improvement in both the open-circuit voltage (Voc) and the fill factor (FF) was observed in the DSSC with the 5 min-soaked photoanode, compared with those of the control cell without any modification. The UV-visible absorbance spectra, UPS valence band spectra, and dark c ...[more]

PMID: 32224956

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Project description:The dye-sensitized solar cell (DSSC) is a potential alternative to the widely used Si-based solar cell, with several advantages including higher energy conversion efficiency under weak and indirect illumination conditions, and the possibility of practical application in urban life due to their exterior characteristics. However, despite these advantages, the energy conversion efficiency of DSSCs has remained low at ∼10%. To improve the efficiency of DSSCs, research has been done on modifying the materials used in DSSC component parts, such as the photoanode, electrolyte, and counter electrode. Another approach is to modify the photoanode to increase the diffusion coefficient, reduce the recombination rate, and enhance the light behavior. One of the most popular methods for improving the efficiency of DSSCs is by trapping and dispersing the incident light using a scattering layer. Use of a scattering layer has shown various and interesting results, depending on the application, but it is currently used only in a simple form and there has been no deep research on the further potential of the scattering layer. In this study, the scattering center was introduced to maximize the effect of scattering. Light distribution near the scattering center, within or on the photoanode, was investigated using finite differential time domain (FDTD) numerical methods. Based on the FDTD analysis, an optimized, dome-shaped three-dimensional modified structure of a transparent photoanode with minimized scattering centers was introduced and indicated the possibility of modifying the photon distribution in the photoanode to enhance the performance of DSSCs. In addition to using the scattering center, we have introduced the structure of the dome-shaped three-dimensional structure to utilize the light distribution within the photoanode. This novel three-dimensional transparent photoanode and scattering center design increased the energy conversion efficiency of DSSCs from 6.3 to 7.2%. These results provide a foundation for investigating the role of the scattering center via further in-depth research. This new three-dimensional photoanode design provides a means to overcome the previous limitations on DSSC performance.

Dataset Information

Enhanced Power Conversion Efficiency of Dye-Sensitized Solar Cells by Band Edge Shift of TiO₂ Photoanode.

Publications

Enhanced Power Conversion Efficiency of Dye-Sensitized Solar Cells by Band Edge Shift of TiO<sub>2</sub> Photoanode.

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