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Removal of Boron and Manganese Ions from Wet-Flue Gas Desulfurization Wastewater by Hybrid Chitosan-Zirconium Sorbent.

ABSTRACT: Flue gas desulfurization (FGD) wastewater, after the alkaline precipitation and coagulation processes, often requires additional treatment in order to reduce the concentrations of boron and heavy metals below the required limits. In this study, we present an innovative and environmentally friendly method for boron and manganese removal that is based on a hybrid chitosan-zirconium hydrogel sorbent. The results from the batch adsorption experiment indicated that the uptake capacity for boron and manganese was equal to 1.61 mg/g and 0.75 mg/g, respectively, while the column study indicated that the total capacity of boron and manganese was equal to 1.89 mg/g and 0.102 mg/g, respectively. The very good applicability of the Langmuir isotherm at 25 °C suggested the monolayer coverage of the boron species onto the hybrid chitosan-zirconium hydrogel with a maximum adsorptive capacity of 2 mg/g. The amounts of boron and manganese in purified water could be decreased to less than 1 mg/dm3 and 0.05 mg/dm3, respectively, starting from the initial concentration of boron equal to 24.7 mg/dm3 and manganese equal to 3.0 mg/dm3 in FGD wastewater. Selective desorption of boron from the loaded bed was favorable when a NaOH solution was used, while manganese was preferentially eluted with a HCl solution. It is important to note that such an innovative method was investigated for the first time by testing borax recovery from wastewater in terms of an eco-technological perspective.

SUBMITTER: Kluczka J

PROVIDER: S-EPMC7183067 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature

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Removal of Boron and Manganese Ions from Wet-Flue Gas Desulfurization Wastewater by Hybrid Chitosan-Zirconium Sorbent.

Kluczka Joanna J

Polymers 20200310 3

Flue gas desulfurization (FGD) wastewater, after the alkaline precipitation and coagulation processes, often requires additional treatment in order to reduce the concentrations of boron and heavy metals below the required limits. In this study, we present an innovative and environmentally friendly method for boron and manganese removal that is based on a hybrid chitosan-zirconium hydrogel sorbent. The results from the batch adsorption experiment indicated that the uptake capacity for boron and m ...[more]

PMID: 32164366

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Project description:Water contaminated with heavy metal ions is extremely poisonous and threatens living organisms. Therefore, scientists place a premium on removing heavy metal ions from water that has already been contaminated. Removing metal ions from water typically involves the use of nanomaterials. Chitosan was made by extracting it from shrimp shells and combining it with a 3 : 1 ratio of synthetically produced AgNPs/GO. Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) with transmission electron microscopy (TEM), and X-ray diffraction were used to investigate an AgNPs/GO/chitosan nanocomposite (XRD). A number of studies must be run to determine the optimal pH, adsorbent quantity, retention period, stirring speed, temperature, and initial concentration. The studies were conducted in a variety of ways. The isotherms of Langmuir, Freundlich, and Dubinin-Radushkevich were utilized. The industrial wastewater was used in the column adsorption experiment, and the flow rates and column bed heights were varied. An optimum contact time, pH, and adsorbent dosage for Mn(ii) were determined. At 30 minutes, pH 6, and 0.05 grams of Mn(ii) adsorbent per 100 ml, with agitation at 250 rpm, room temperature of 30 °C, and an initial concentration of 40 ppm, the best conditions were discovered. A positive correlation coefficient finding (R 2 = 0.925) indicates a good fit for Mn, according to equilibrium studies (II). The pseudo-second-order active model was connected to data that suited the pseudo-first and pseudo-second-order models. In the intra-particle diffusion model, the mechanism must proceed through four phases before equilibrium is reached. In an industrial adsorbent column, the adsorbent was put to the test. The periodicity test demonstrates that the nanocomposite's adsorption capability can be recovered by washing it with 0.1 M HCl. Mn(ii) adsorbed on AgNPs/GO/Chitosan after four cycles was only 20%, insufficient for additional adsorption tests. The repeated cycles that led to the partial loss of the adsorbate may have reduced the adsorbent material's efficacy.

Dataset Information

Removal of Boron and Manganese Ions from Wet-Flue Gas Desulfurization Wastewater by Hybrid Chitosan-Zirconium Sorbent.

Publications

Removal of Boron and Manganese Ions from Wet-Flue Gas Desulfurization Wastewater by Hybrid Chitosan-Zirconium Sorbent.

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