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All-Small-Molecule Organic Solar Cells Based on a Fluorinated Small Molecule Donor With High Open-Circuit Voltage of 1.07 V.

ABSTRACT: A new small molecule donor with an acceptor-donor-acceptor (A-D-A) structure, namely DRTB-FT, has been designed and synthesized for all-small-molecule organic solar cells (ASM-OSCs). By introducing fluorine atoms on the thienyl substituent of the central benzodithiophene unit, DRTB-FT shows a low-lying highest occupied molecular orbital (HOMO) energy level of -5.64 eV. Blending with an A-D-A type acceptor F-2Cl, DRTB-FT based ASM-OSCs gave a power conversion efficiency (PCE) of 7.66% with a high open-circuit voltage (V oc) of 1.070 V and a low energy loss of 0.47 eV. The results indicate that high V oc of ASM-OSC devices can be obtained through careful donor molecular optimization.

SUBMITTER: Liu C

PROVIDER: S-EPMC7198867 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature

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All-Small-Molecule Organic Solar Cells Based on a Fluorinated Small Molecule Donor With High Open-Circuit Voltage of 1.07 V.

Liu Chunyan C Qiu Nailiang N Sun Yanna Y Ke Xin X Zhang Hongtao H Li Chenxi C Wan Xiangjian X Chen Yongsheng Y

Frontiers in chemistry 20200428

A new small molecule donor with an acceptor-donor-acceptor (A-D-A) structure, namely DRTB-FT, has been designed and synthesized for all-small-molecule organic solar cells (ASM-OSCs). By introducing fluorine atoms on the thienyl substituent of the central benzodithiophene unit, DRTB-FT shows a low-lying highest occupied molecular orbital (HOMO) energy level of -5.64 eV. Blending with an A-D-A type acceptor F-2Cl, DRTB-FT based ASM-OSCs gave a power conversion efficiency (PCE) of 7.66% with a high ...[more]

PMID: 32411669

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