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MWCNT-Supported PVP-Capped Pd Nanoparticles as Efficient Catalysts for the Dehydrogenation of Formic Acid.

ABSTRACT: Various carbon materials were used as support of polyvinylpyrrolidone (PVP)-capped Pd nanoparticles for the synthesis of catalysts for the production of hydrogen from formic acid dehydrogenation reaction. Among investigated, MWCNT-supported catalysts were the most promising, with a TOF of 1430 h-1 at 80°C. The presence of PVP was shown to play a positive role by increasing the hydrophilicity of the materials and enhancing the interface contact between the reactant molecules and the catalytic active sites.

SUBMITTER: Ortega-Murcia A

PROVIDER: S-EPMC7199183 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature

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MWCNT-Supported PVP-Capped Pd Nanoparticles as Efficient Catalysts for the Dehydrogenation of Formic Acid.

Ortega-Murcia Alejandro A Navlani-García Miriam M Morallón Emilia E Cazorla-Amorós Diego D

Frontiers in chemistry 20200428

Various carbon materials were used as support of polyvinylpyrrolidone (PVP)-capped Pd nanoparticles for the synthesis of catalysts for the production of hydrogen from formic acid dehydrogenation reaction. Among investigated, MWCNT-supported catalysts were the most promising, with a TOF of 1430 h-1 at 80°C. The presence of PVP was shown to play a positive role by increasing the hydrophilicity of the materials and enhancing the interface contact between the reactant molecules and the ca ...[more]

PMID: 32411676

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