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Crystal structure and Hirshfeld surface analysis of 6-benzoyl-3,5-di-phenyl-cyclo-hex-2-en-1-one.

ABSTRACT: In the title compound, C25H20O2, the central cyclo-hexenone ring adopts an envelope conformation. The mean plane of the cyclo-hexenone ring makes dihedral angles of 87.66?(11) and 23.76?(12)°, respectively, with the two attached phenyl rings, while it is inclined by 69.55?(11)° to the phenyl ring of the benzoyl group. In the crystal, the mol-ecules are linked by C-H?O and C-H?? inter-actions, forming a three-dimensional network.

SUBMITTER: Naghiyev FN

PROVIDER: S-EPMC7199244 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature

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Crystal structure and Hirshfeld surface analysis of 6-benzoyl-3,5-di-phenyl-cyclo-hex-2-en-1-one.

Naghiyev Farid N FN Akkurt Mehmet M Askerov Rizvan K RK Mamedov Ibrahim G IG Rzayev Rovnag M RM Chyrka Taras T Maharramov Abel M AM

Acta crystallographica. Section E, Crystallographic communications 20200421 Pt 5

In the title compound, C25H20O2, the central cyclo-hexenone ring adopts an envelope conformation. The mean plane of the cyclo-hexenone ring makes dihedral angles of 87.66 (11) and 23.76 (12)°, respectively, with the two attached phenyl rings, while it is inclined by 69.55 (11)° to the phenyl ring of the benzoyl group. In the crystal, the mol-ecules are linked by C-H⋯O and C-H⋯π inter-actions, forming a three-dimensional network. ...[more]

PMID: 32431939

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Crystal structure and Hirshfeld surface analysis of 3,3',3''-[(1,3,5-triazine-2,4,6-tri-yl)tris-(-oxy)]tris-(5,5-di-methyl-cyclo-hex-2-en-1-one).

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Syntheses and structures of two benzoyl amides: 2-chloro-4-eth-oxy-3,5-dimeth-oxy-N-(3-oxo-cyclo-hex-1-en-1-yl)benzamide and 2-chloro-N-(5,5-dimethyl-3-oxo-cyclo-hex-1-en-1-yl)-4-eth-oxy-3,5-di-meth-oxy-benzamide.

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