Ontology highlight
ABSTRACT:
SUBMITTER: Yi H
PROVIDER: S-EPMC7199387 | biostudies-literature | 2020 Feb
REPOSITORIES: biostudies-literature
Yi Heng H Hu Pengfei P Snyder Scott A SA
Angewandte Chemie (International ed. in English) 20200108 7
Pd-catalyzed sequences involving oxidative addition, cyclization, and termination through intermolecular nucleophile capture have tremendous utility. Indeed, they can generate a plethora of different polycyclic structures possessing a diverse range of functionality. However, one area of deficiency for Pd<sup>0</sup> /Pd<sup>II</sup> variants is the ability to conclude them with oxygen-based species. Inspired by the recent discovery of one such reaction in the course of a total synthesis program, ...[more]