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Optimization of CO2 Adsorption on Solid-Supported Amines and Thermal Regeneration Mode Comparison.

ABSTRACT: For improving the CO2 adsorption capacity of solid-supported amines, five commercial porous supports have been selected and impregnated with tetraethylenepentamine (TEPA), and their CO2 adsorption performances have been evaluated using a fixed-bed reactor coupled with mass spectrometry. For solid-supported amines, CO2 adsorption capacities coincide with the texture characterization of the adsorbent supports (mesoporous alumina, montmorillonite, silica gel, porous resin, MCM-41 molecular sieve), and the optimum TEPA loading amount is mainly affected by the pore volume. The mesoporous supports were found to be more conducive to uniform loading of organic amine, with more than 370 mg/g CO2 adsorbed per unit TEPA. Other components in flue gas, especially H2O, favor CO2 adsorption on solid-supported amines. SO2 inhibited the CO2 adsorption, which was mainly attributable to the strong and irreversible binding of SO2 on some amine sites. NO had little effect on CO2 adsorption. Thermal stabilities of solid-supported amines have been tested based on thermogravimetry curves, and the main weight loss peak for TEPA appears at 513 K for solid-supported amines. Linear and step regeneration modes have been compared, revealing that the temperature for step regeneration is 37 K lower than that for the linear regeneration mode. Moreover, the desorption peak area for the step regeneration mode is 20% higher than that for the linear regeneration mode, indicating that the step regeneration mode can be used in practical applications, to reduce energy consumption during regeneration.

SUBMITTER: Guo Y

PROVIDER: S-EPMC7203696 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature

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Optimization of CO2 Adsorption on Solid-Supported Amines and Thermal Regeneration Mode Comparison.

Guo Yangyang Y Luo Lei L Zheng Yang Y Zhu Tingyu T

ACS omega 20200420 17

For improving the CO2 adsorption capacity of solid-supported amines, five commercial porous supports have been selected and impregnated with tetraethylenepentamine (TEPA), and their CO2 adsorption performances have been evaluated using a fixed-bed reactor coupled with mass spectrometry. For solid-supported amines, CO2 adsorption capacities coincide with the texture characterization of the adsorbent supports (mesoporous alumina, montmorillonite, silica gel, porous ...[more]

PMID: 32391449

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Project description:In this work, a rapid method for the simultaneous determination of N and S in seafood was established based on a solid sampling absorption-desorption system coupled with a thermal conductivity detector. This setup mainly includes a solid sampling system, a gas line unit for controlling high-purity oxygen and helium, a combustion and reduction furnace, a purification column system for moisture, halogen, SO2, and CO2, and a thermal conductivity detector. After two stages of purging with 20 s of He sweeping (250 mL/min), N2 residue in the sample-containing chamber can be reduced to <0.01% to improve the device’s analytical sensitivity and precision. Herein, 100 s of heating at 900 °C was chosen as the optimized decomposition condition. After the generated SO2, H2O, and CO2 were absorbed by the adsorption column in turn, the purification process executed the vaporization of the N-containing analyte, and then N2 was detected by the thermal conductivity cell for the quantification of N. Subsequently, the adsorbed SO2 was released after heating the SO2 adsorption column and then transported to the thermal conductivity cell for the detection and quantification of S. After the instrumental optimization, the linear range was 2.0–100 mg and the correlation coefficient (R) was more than 0.999. The limit of detection (LOD) for N was 0.66 μg and the R was less than 4.0%, while the recovery rate ranged from 95.33 to 102.8%. At the same time, the LOD for S was 2.29 μg and the R was less than 6.0%, while the recovery rate ranged from 92.26 to 105.5%. The method was validated using certified reference materials (CRMs) and the measured N and S concentrations agreed with the certified values. The method indicated good accuracy and precision for the simultaneous detection of N and S in seafood samples. The total time of analysis was less than 6 min without the sample preparation process, fulfilling the fast detection of N and S in seafood. The establishment of this method filled the blank space in the area of the simultaneous and rapid determination of N and S in aquatic product solids. Thus, it provided technical support effectively to the requirements of risk assessment and detection in cases where supervision inspection was time-dependent.

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Optimization of CO2 Adsorption on Solid-Supported Amines and Thermal Regeneration Mode Comparison.

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Optimization of CO<sub>2</sub> Adsorption on Solid-Supported Amines and Thermal Regeneration Mode Comparison.

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