Browse
Submit Data
Databases
API
Help

Dataset Information

22 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Biomass-Derived P/N-Co-Doped Carbon Nanosheets Encapsulate Cu3P Nanoparticles as High-Performance Anode Materials for Sodium-Ion Batteries.

ABSTRACT: Biomass-derived approaches have been accepted as a practical way for the design of transitional metal phosphides confined by carbon matrix (TMPs@C) as energy storage materials. Herein, we successfully synthesize P/N-co-doped carbon nanosheets encapsulating Cu3P nanoparticles (Cu3P@P/N-C) by a feasible aqueous reaction followed by a phosphorization procedure using sodium alginate as the biomass carbon source. Cu-alginate hydrogel balls can be squeezed into two-dimensional (2D) nanosheets through a freeze-drying process. Then, Cu3P@P/N-C was obtained after the phosphorization procedure. This rationally designed structure not only improved the kinetics of ion/electron transportation but also buffered the volume expansion of Cu3P nanoparticles during the continuous charge and discharge processes. In addition, the 2D P/N co-doped carbon nanosheets can also serve as a conductive matrix, which can enhance the electronic conductivity of the whole electrode as well as provide rapid channels for electron/ion diffusion. Thus, when applied as anode materials for sodium-ion batteries, it exhibited remarkable cycling stability and rate performance. Prominently, Cu3P@P/N-C demonstrated an outstanding reversible capacity of 209.3 mAh g-1 at 1 A g-1 after 1,000 cycles. Besides, it still maintained a superior specific capacity of 118.2 mAh g-1 after 2,000 cycles, even at a high current density of 5 A g-1.

SUBMITTER: Yin Y

PROVIDER: S-EPMC7216970 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Large-Area Carbon Nanosheets Doped with Phosphorus: A High-Performance Anode Material for Sodium-Ion Batteries.

Project description:Large-area phosphorus-doped carbon nanosheets (P-CNSs) are first obtained from carbon dots (CDs) through self-assembly driving from thermal treatment with Na catalysis. This is the first time to realize the conversion from 0D CDs to 2D nanosheets doped with phosphorus. The sodium storage behavior of phosphorus-doped carbon material is also investigated for the first time. As anode material for sodium-ion batteries (SIBs), P-CNSs exhibit superb performances for electrochemical storage of sodium. When cycled at 0.1 A g-1, the P-CNSs electrode delivers a high reversible capacity of 328 mAh g-1, even at a high current density of 20 A g-1, a considerable capacity of 108 mAh g-1 can still be maintained. Besides, this material also shows excellent cycling stability, at a current density of 5 A g-1, the reversible capacity can still reach 149 mAh g-1 after 5000 cycles. This work will provide significant value for the development of both carbon materials and SIBs anode materials.

| S-EPMC5238737 | biostudies-literature

Nitrogen-Doped Carbon for Red Phosphorous Based Anode Materials for Lithium Ion Batteries.

Project description:Serving as conductive matrix and stress buffer, the carbon matrix plays a pivotal role in enabling red phosphorus to be a promising anode material for high capacity lithium ion batteries and sodium ion batteries. In this paper, nitrogen-doping is proved to effective enhance the interface interaction between carbon and red phosphorus. In detail, the adsorption energy between phosphorus atoms and oxygen-containing functional groups on the carbon is significantly reduced by nitrogen doping, as verified by X-ray photoelectron spectroscopy. The adsorption mechanisms are further revealed on the basis of DFT (the first density functional theory) calculations. The RPNC (red phosphorus/nitrogen-doped carbon composite) material shows higher cycling stability and higher capacity than that of RPC (red phosphorus/carbon composite) anode. After 100 cycles, the RPNC still keeps discharge capacity of 1453 mAh g-1 at the current density of 300 mA g-1 (the discharge capacity of RPC after 100 cycles is 1348 mAh g-1). Even at 1200 mA g-1, the RPNC composite still delivers a capacity of 1178 mAh g-1. This work provides insight information about the interface interactions between composite materials, as well as new technology develops high performance phosphorus based anode materials.

| S-EPMC5793632 | biostudies-literature

Double Morphology of Co9S8 Coated by N, S Co-doped Carbon as Efficient Anode Materials for Sodium-Ion Batteries.

Project description:Co9S8 is a potential anode material for its high sodium storage performance, easy accessibility, and thermostability. However, the volume expansion is a great hindrance to its development. Herein, a composite containing Co9S8 nanofibers and hollow Co9S8 nanospheres with N, S co-doped carbon layer (Co9S8@NSC) is successfully synthesized through a facile solvothermal process and a high-temperature carbonization. Ascribed to the carbon coating and the large specific surface area, severe volume stress can be effectively alleviated. In particular, with N and S heteroatoms introduced into the carbon layer, which is conducive to the Na+ adsorption and diffusion on the carbon surface, Co9S8@NSC can perform more capacitive sodium storage mechanism. As a result, the electrode can exhibit a favorable reversible capacity of 226?mA?h?g-1 at 5 A g-1 and a favorable capacity retention of 83.1% at 1 A g-1 after 800?cycles. The unique design provides an innovative thought for enhancing the sodium storage performance.

| S-EPMC6975880 | biostudies-literature

N/S-Co-Doped Porous Carbon Sheets Derived from Bagasse as High-Performance Anode Materials for Sodium-Ion Batteries.

Project description:Heteroatom doping is considered to be an efficient strategy to improve the electrochemical performance of carbon-based anode materials for Na-ion batteries (SIBs), due to the introduction of an unbalanced electron atmosphere and increased electrochemical reactive sites of carbon. However, developing green and low-cost approaches to synthesize heteroatom dual-doped carbon with an appropriate porous structure, is still challenging. Here, N/S-co-doped porous carbon sheets, with a main pore size, in the range 1.8-10 nm, has been fabricated through a simple thermal treatment method, using KOH-treated waste bagasse, as a carbon source, and thiourea, as the N and S precursor. The N/S-co-doped carbon sheet electrodes possess significant defects, high specific surface area, enhanced electronic conductivity, improved sodium storage capacity, and long-term cyclability, thereby delivering a high capacity of 223 mA h g-1 at 0.2 A g-1 after 500 cycles and retaining 155 mA h g-1 at 1 A g-1 for 2000 cycles. This work provides a low-cost route to fabricate high-performance dual-doped porous carbonaceous anode materials for SIBs.

| S-EPMC6781196 | biostudies-literature

Low-Cost and High-Performance Hard Carbon Anode Materials for Sodium-Ion Batteries.

Project description:As an anode material for sodium-ion batteries (SIBs), hard carbon (HC) presents high specific capacity and favorable cycling performance. However, high cost and low initial Coulombic efficiency (ICE) of HC seriously limit its future commercialization for SIBs. A typical biowaste, mangosteen shell was selected as a precursor to prepare low-cost and high-performance HC via a facile one-step carbonization method, and the influence of different heat treatments on the morphologies, microstructures, and electrochemical performances was investigated systematically. The microstructure evolution studied using X-ray diffraction, Raman, Brunauer-Emmett-Teller, and high-resolution transmission electron microscopy, along with electrochemical measurements, reveals the optimal carbonization condition of the mangosteen shell: HC carbonized at 1500 °C for 2 h delivers the highest reversible capacity of ∼330 mA h g-1 at a current density of 20 mA g-1, a capacity retention of ∼98% after 100 cycles, and an ICE of ∼83%. Additionally, the sodium-ion storage behavior of HC is deeply analyzed using galvanostatic intermittent titration and cyclic voltammetry technologies.

| S-EPMC6641066 | biostudies-literature

Hierarchical Nitrogen-Doped Porous Carbon Microspheres as Anode for High Performance Sodium Ion Batteries.

Project description:Sodium ion batteries (SIBs) have been considered as a promising alternative to lithium ion batteries (LIBs) for large scale energy storage in the future. However, the commercial graphite anode is not suitable for SIBs because of its low Na+ ions storage capability and poor cycling stability. Recently, another alternative as anode for SIBs, amorphous carbon materials, have attracted tremendous attention because of their abundant resource, nontoxicity, and most importantly, stability. Here, N-doped hierarchical porous carbon microspheres (NHPCS) derived from Ni-MOF have been prepared and used as anode for SIBs. Benefiting from the open porous structure and expanded interlayer distance, the diffusion of Na+ is greatly facilitated and the Na+ storage capacity is significantly enhanced concurrently. The NHPCS exhibit high reversible capacity (291 mA h g-1 at current of 200 mA g-1), excellent rate performance (256 mA h g-1 at high current of 1,000 mA g-1), and outstanding cycling stability (204 mA h g-1 after 200 cycles).

| S-EPMC6834544 | biostudies-literature

Three-Dimensional SnS Decorated Carbon Nano-Networks as Anode Materials for Lithium and Sodium Ion Batteries.

Project description:The three-dimensional (3D) SnS decorated carbon nano-networks (SnS@C) were synthesized via a facile two-step method of freeze-drying combined with post-heat treatment. The lithium and sodium storage performances of above composites acting as anode materials were investigated. As anode materials for lithium ion batteries, a high reversible capacity of 780 mAh·g-1 for SnS@C composites can be obtained at 100 mA·g-1 after 100 cycles. Even cycled at a high current density of 2 A·g-1, the reversible capacity of this composite can be maintained at 610 mAh·g-1 after 1000 cycles. The initial charge capacity for sodium ion batteries can reach 333 mAh·g-1, and it retains a reversible capacity of 186 mAh·g-1 at 100 mA·g-1 after 100 cycles. The good lithium or sodium storage performances are likely attributed to the synergistic effects of the conductive carbon nano-networks and small SnS nanoparticles.

| S-EPMC5869626 | biostudies-literature

N/S Co-doped Carbon Derived From Cotton as High Performance Anode Materials for Lithium Ion Batteries.

Project description:Highly porous carbon with large surface areas is prepared using cotton as carbon sources which derived from discard cotton balls. Subsequently, the sulfur-nitrogen co-doped carbon was obtained by heat treatment the carbon in presence of thiourea and evaluated as Lithium-ion batteries anode. Benefiting from the S, N co-doping, the obtained S, N co-doped carbon exhibits excellent electrochemical performance. As a result, the as-prepared S, N co-doped carbon can deliver a high reversible capacity of 1,101.1 mA h g-1 after 150 cycles at 0.2 A g-1, and a high capacity of 531.2 mA h g-1 can be observed even after 5,000 cycles at 10.0 A g-1. Moreover, excellently rate capability also can be observed, a high capacity of 689 mA h g-1 can be obtained at 5.0 A g-1. This superior lithium storage performance of S, N co-doped carbon make it as a promising low-cost and sustainable anode for high performance lithium ion batteries.

| S-EPMC5932144 | biostudies-literature

Sulfur-Doped Carbon with Enlarged Interlayer Distance as a High-Performance Anode Material for Sodium-Ion Batteries.

Project description:S-doped carbon is investigated as a high-performance anode material for sodium-ion batteries. Due to the introduction of a high-content of S atoms, the as-obtained S-doped carbon shows an enlarged interlayer distance. As an anode, a high specific capacity of up to 303 mAh g-1 is achieved, even after 700 cycles at 0.5 A g-1.

| S-EPMC5049484 | biostudies-literature

MoS<sub>2</sub>-Coupled Carbon Nanosheets Encapsulated on Sodium Titanate Nanowires as Super-Durable Anode Material for Sodium-Ion Batteries.

Project description:There is an ever-increasing demand for rechargeable batteries with fast charging, long cycling, high safety, and low cost in new energy storage systems. Herein, a heterogeneous architecture composed of MoS2-coupled carbon nanosheets encapsulated on sodium titanate nanowires is developed and demonstrated as an advanced anode for sodium-ion batteries (SIBs). Owing to the synergistic effects of ultrastable substrate of 1D sodium titanate (NTO) nanowires, high-capacity promoter of 2D MoS2 nanosheets as well as the 2D conductive carbon matrix, the resulting 1D/2D-2D hybrid demonstrates excellent high-rate capacity and super-durable cyclability, delivering a stable capacity of up to 425.5 mAh g-1 at 200 mA g-1. Even at an ultrafast charging/discharging process within 80 s, the capacity can be maintained at 201 mAh g-1 after 16 000 cycles with only 0.0012% capacity loss per cycle, one of the best high-rate capacities and cyclabilities for NTO-based hybrid composites. The present work highlights the designing protocol of hierarchical nanoarchitectures with stable substrate and high-capacity electrodes for next-generation energy storage applications.

| S-EPMC6523371 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data