Ontology highlight
ABSTRACT:
SUBMITTER: van Alten RS
PROVIDER: S-EPMC7217231 | biostudies-literature | 2020 Apr
REPOSITORIES: biostudies-literature
European journal of inorganic chemistry 20200131 15-16
The splitting of N<sub>2</sub> into well-defined terminal nitride complexes is a key reaction for nitrogen fixation at ambient conditions. In continuation of our previous work on rhenium pincer mediated N<sub>2</sub> splitting, nitrogen activation and cleavage upon (electro)chemical reduction of [ReCl<sub>2</sub>(<i>L</i>2)] {<i>L</i>2 = N(CHCHP<i>t</i>Bu<sub>2</sub>)<sub>2</sub> <sup>-</sup>} is reported. The electrochemical characterization of [ReCl<sub>2</sub>(<i>L</i>2)] and comparison with ...[more]