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Theoretical Investigation of Energetic Salts with Pentazolate Anion.


ABSTRACT: Energetic salts based on pentazolate anion (cyclo-N5-) have attracted much attention due to their high nitrogen contents. However, it is an enormous challenge to efficiently screen out an appropriate cation that can match well with cyclo-N5-. The vertical electron affinity (VEA) of the cations and vertical ionization potential (VIP) of the anions for 135 energetic salts and some cyclo-N5- salts were calculated by the density functional theory (DFT). The magnitudes of VEA and VIP, and their matchability were analyzed. The results based on the calculations at the B3LYP/6-311++G(d,p) and B3LYP/aug-cc-pVTZ levels indicate that there is an excellent compatibility between cyclo-N5- and cation when the difference between the VEA of cation and the VIP of cyclo-N5- anion is -2.8 to -1.0 eV. The densities of the salts were predicted by the DFT method. Relationship between the calculated density and the experimental density was established as ?Expt = 1.111?cal - 0.06067 with a correlation coefficient of 0.905. This regression equation could be in turn used to calibrate the calculated density of the cyclo-N5- energetic salts accurately. This work provides a favorable way to explore the energetic salts with excellent performance based on cyclo-N5-.

SUBMITTER: Wang HR 

PROVIDER: S-EPMC7221799 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature

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Theoretical Investigation of Energetic Salts with Pentazolate Anion.

Wang Hao-Ran HR   Zhang Chong C   Hu Bing-Cheng BC   Ju Xue-Hai XH  

Molecules (Basel, Switzerland) 20200413 8


Energetic salts based on pentazolate anion (<i>cyclo</i>-N<sub>5</sub><sup>-</sup>) have attracted much attention due to their high nitrogen contents. However, it is an enormous challenge to efficiently screen out an appropriate cation that can match well with <i>cyclo</i>-N<sub>5</sub><sup>-</sup>. The vertical electron affinity (<i>VEA</i>) of the cations and vertical ionization potential (<i>VIP</i>) of the anions for 135 energetic salts and some <i>cyclo</i>-N<sub>5</sub><sup>-</sup> salts w  ...[more]

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