Ontology highlight
ABSTRACT:
SUBMITTER: Danowski W
PROVIDER: S-EPMC7232677 | biostudies-literature | 2020 May
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20200505 19
The visible-light-driven rotation of an overcrowded alkene-based molecular motor strut in a dual-function metal-organic framework (MOF) is reported. Two types of functional linkers, a palladium-porphyrin photosensitizer and a bispyridine-derived molecular motor, were used to construct the framework capable of harvesting low-energy green light to power the rotary motion. The molecular motor was introduced in the framework using the postsynthetic solvent-assisted linker exchange (SALE) method, and ...[more]