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Finding the equilibrium of organic electrochemical transistors.

ABSTRACT: Organic Electrochemical Transistors are versatile sensors that became essential for the field of organic bioelectronics. However, despite their importance, an incomplete understanding of their working mechanism is currently precluding a targeted design of Organic Electrochemical Transistors and it is still challenging to formulate precise design rules guiding materials development in this field. Here, it is argued that current capacitive device models neglect lateral ion currents in the transistor channel and therefore fail to describe the equilibrium state of Organic Electrochemical Transistors. An improved model is presented, which shows that lateral ion currents lead to an accumulation of ions at the drain contact, which significantly alters the transistor behavior. Overall, these results show that a better understanding of the interface between the organic semiconductor and the drain electrode is needed to reach a full understanding of Organic Electrochemical Transistors.

SUBMITTER: Kaphle V

PROVIDER: S-EPMC7239912 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature

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Finding the equilibrium of organic electrochemical transistors.

Kaphle Vikash V Paudel Pushpa Raj PR Dahal Drona D Radha Krishnan Raj Kishen RK Lüssem Björn B

Nature communications 20200520 1

Organic Electrochemical Transistors are versatile sensors that became essential for the field of organic bioelectronics. However, despite their importance, an incomplete understanding of their working mechanism is currently precluding a targeted design of Organic Electrochemical Transistors and it is still challenging to formulate precise design rules guiding materials development in this field. Here, it is argued that current capacitive device models neglect lateral ion currents in the transist ...[more]

PMID: 32433542

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Project description:Organic electrochemical transistors (OECTs) are signal transducers offering high amplification, which makes them particularly advantageous for detecting weak biological signals. While OECTs typically operate with aqueous electrolytes, those employing solid-like gels as the dielectric layer can be excellent candidates for constructing wearable electrophysiology probes. Despite their potential, the impact of the gel electrolyte type and composition on the operation of the OECT and the associated device design considerations for optimal performance with a chosen electrolyte have remained ambiguous. In this work, we investigate the influence of three types of gel electrolytes-hydrogels, eutectogels, and iongels, each with varying compositions on the performance of OECTs. Our findings highlight the superiority of the eutectogel electrolyte, which comprises poly(glycerol 1,3-diglycerolate diacrylate) as the polymer matrix and choline chloride in combination with 1,3-propanediol deep eutectic solvent as the ionic component. This eutectogel electrolyte outperforms hydrogel and iongel counterparts of equivalent dimensions, yielding the most favorable transient and steady-state performance for both p-type depletion and p-type/n-type enhancement mode transistors gated with silver/silver chloride (Ag/AgCl). Furthermore, the eutectogel-integrated enhancement mode OECTs exhibit exceptional operational stability, reflected in the absence of signal-to-noise ratio (SNR) variation in the simulated electrocardiogram (ECG) recordings conducted continuously over a period of 5 h, as well as daily measurements spanning 30 days. Eutectogel-based OECTs also exhibit higher ECG signal amplitudes and SNR than their counterparts, utilizing the commercially available hydrogel, which is the most common electrolyte for cutaneous electrodes. These findings underscore the potential of eutectogels as a semisolid electrolyte for OECTs, particularly in applications demanding robust and prolonged physiological signal monitoring.

Dataset Information

Finding the equilibrium of organic electrochemical transistors.

Publications

Finding the equilibrium of organic electrochemical transistors.

Similar Datasets

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