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Influence of Mo addition on the structural and electrochemical performance of Ni-rich cathode material for lithium-ion batteries.


ABSTRACT: Molybdenum modified LiNi0.84Co0.11Mn0.05O2 cathode with different doping concentrations (0-5 wt.%) is successfully prepared and its electrochemical performances are investigated. It is demonstrated that molybdenum in LiNi0.84Co0.11Mn0.05O2 has a positive effect on structural stability and extraordinary electrochemical performances, including improved long-term cycling and high-rate capability. Among all samples, the 1 wt. % molybdenum LiNi0.84Co0.11Mn0.05O2 delivers superior initial discharge capacity of 205 mAh g-1 (0.1?C), cycling stability of 89.5% (0.5?C) and rate capability of 165 mAh g-1 (2?C) compared to those of others. Therefore, we can conclude that the 1 wt. % molybdenum is an effective strategy for Ni-rich LiNi0.84Co0.11Mn0.05O2 cathode used in lithium ion batteries.

SUBMITTER: Sattar T 

PROVIDER: S-EPMC7244510 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature

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Influence of Mo addition on the structural and electrochemical performance of Ni-rich cathode material for lithium-ion batteries.

Sattar Tahir T   Lee Seung-Hwan SH   Jin Bong-Soo BS   Kim Hyun-Soo HS  

Scientific reports 20200522 1


Molybdenum modified LiNi<sub>0.84</sub>Co<sub>0.11</sub>Mn<sub>0.05</sub>O<sub>2</sub> cathode with different doping concentrations (0-5 wt.%) is successfully prepared and its electrochemical performances are investigated. It is demonstrated that molybdenum in LiNi<sub>0.84</sub>Co<sub>0.11</sub>Mn<sub>0.05</sub>O<sub>2</sub> has a positive effect on structural stability and extraordinary electrochemical performances, including improved long-term cycling and high-rate capability. Among all sampl  ...[more]

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