Ontology highlight
ABSTRACT:
SUBMITTER: Zhang W
PROVIDER: S-EPMC7244735 | biostudies-literature | 2020 May
REPOSITORIES: biostudies-literature
Nature communications 20200522 1
Vinylboronates and alkylboronates are key components in variegated transformations in all facets of chemical science. The synthesis of vinylboronates and alkylboronates suffers from step-tedious and poor stereoselective procedures. We have developed a regulated radical difunctionalization strategy for the construction of fluorine-containing vinylboronates and alkylboronates with an integrated redox-active reagent IMDN-SO<sub>2</sub>R<sub>F</sub>. This bench-stable imidazolium sulfonate cationic ...[more]