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ABSTRACT:
SUBMITTER: Yambulatov DS
PROVIDER: S-EPMC7249109 | biostudies-literature | 2020 Apr
REPOSITORIES: biostudies-literature
Molecules (Basel, Switzerland) 20200428 9
Complexes [(dpp-BIAN)<sup>0</sup>Co<sup>II</sup>I<sub>2</sub>]·MeCN (<b>I</b>) and [(Py)<sub>2</sub>CoI<sub>2</sub>] (<b>II</b>) were synthesized by the reaction between cobalt(II) iodide and 1,2-bis(2,6-diisopropylphenylimino)acenaphthene (dpp-BIAN) or pyridine (Py), respectively. The molecular structures of the complexes were determined by X-ray diffraction. The Co(II) ions in both compounds are in a distorted tetrahedral environment (CoN<sub>2</sub>I<sub>2</sub>). The electrochemical behavior ...[more]