Ontology highlight
ABSTRACT:
SUBMITTER: Wang D
PROVIDER: S-EPMC7259776 | biostudies-literature | 2020 May
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20200506 20
A systematic study of radical boron migration in diboronate complexes to form synthetically valuable 1,<i>n</i>-bisborylalkanes is reported. The boronate complexes are readily generated by reaction of commercial bis(pinacolato)diboron with alkyl Grignard compounds. C-radical generation at a defined position with respect to the diboron moiety is achieved either via intermolecular H-abstraction with a CF<sub>3</sub>-radical or via alkene perfluoroalkyl radical addition. It is shown that radical 1, ...[more]