Unknown

Dataset Information

0

Crystal structures of 6-cyclo-propyl-1,3-diphenylfulvene and 6-(2,3-di-meth-oxy-naphth-yl)-1,3-di-phenylfulvene.


ABSTRACT: The title compounds, 6-cyclo-propyl-1,3-diphenylfulvene, C21H18, [systematic name: 5-(cyclo-propyl-methyl-idene)-1,3-di-phen-yl-cyclo-penta-1,3-diene], 1, and 6-(2,3-di-meth-oxy-naphth-yl)-1,3-diphenylfulvene, C30H24O2, {systematic name: 5-[(3,4-di-meth-oxy-naphthalen-2-yl)methyl-idene]-1,3-di-phenyl-cyclo-penta-1,3-di-ene}, 2, were prepared from 1,3-di-phenyl-cyclo-penta-diene, pyrrolidine, and the corresponding aldehydes in an ethano-lic solution. Each structure crystallizes with one mol-ecule per asymmetric unit and exhibits the alternating short and long bond lengths typical of fulvenes. A network of C-H⋯C ring inter-actions as well as C-H⋯O inter-actions is observed, resulting in the compact packing found in each structure.

SUBMITTER: Brown LC 

PROVIDER: S-EPMC7273991 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC6775738 | biostudies-literature
| S-EPMC4778832 | biostudies-literature
| S-EPMC3089130 | biostudies-literature
| S-EPMC6323868 | biostudies-literature
| S-EPMC4257384 | biostudies-literature
| S-EPMC3588551 | biostudies-literature
| S-EPMC5598847 | biostudies-literature
| S-EPMC4645031 | biostudies-literature
| S-EPMC2960797 | biostudies-other
| S-EPMC4420130 | biostudies-literature