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Characterization of self-assembled silver nanoparticle ink based on nanoemulsion method.

ABSTRACT: A well-dispersed self-assembled silver nanoparticles (AgNPs) ink with high purity was synthesized via AgNO3 emulsion prepared by blending an AgNO3 aqueous solution and a liquid paraffin solution of both polyoxyethylene (20) sorbitan monooleate (Tween 80) and sorbitan monooleate (Span 80). The ink remained as an emulsion at low temperatures; however, it produced AgNPs after sintering at about 60°C and showed a high stability at nanoscale sizes (with diameters ranging 8.6-13.4 nm) and a high conductivity. During the whole procedure, Tween 80 acted as a surfactant, reductant and stabilizer. Presumably, Tween 80 underwent an autoxidation process, where a free radical of an ?-carbon of ether oxygen was formed by hydrogen abstraction. The mean diameter of emulsion droplets could be reduced by decreasing water content and increasing the ratio of surfactant and concentration of AgNO3 aqueous solution. Consequently, the thermogravimetric analysis and X-ray diffraction result clarified the purity of the produced Ag0. Dynamic light scattering and ultraviolet-visible spectroscopy clarified that an increased concentration of AgNO3 decreased the particle size.

SUBMITTER: Hu D

PROVIDER: S-EPMC7277254 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature

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Characterization of self-assembled silver nanoparticle ink based on nanoemulsion method.

Hu Donghao D Ogawa Kazuyoshi K Kajiyama Mikio M Enomae Toshiharu T

Royal Society open science 20200527 5

A well-dispersed self-assembled silver nanoparticles (AgNPs) ink with high purity was synthesized via AgNO<sub>3</sub> emulsion prepared by blending an AgNO<sub>3</sub> aqueous solution and a liquid paraffin solution of both polyoxyethylene (20) sorbitan monooleate (Tween 80) and sorbitan monooleate (Span 80). The ink remained as an emulsion at low temperatures; however, it produced AgNPs after sintering at about 60°C and showed a high stability at nanoscale sizes (with diameters ranging 8.6-13. ...[more]

PMID: 32537225

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Project description:Gold nanoparticles (AuNPs) with 14, 25 and 40nm diameters were functionalized with different chain length (C6, C8, C11 and C16) carboxylic acid terminated alkanethiol self-assembled monolayers (COOH-SAMs). X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS) were used to examine the changes in surface chemistry as both AuNP diameter and SAM chain length were varied. COOH-SAMs on flat gold surfaces were also examined and compared to the COOH-SAM on AuNP results. For a given surface, as the COOH-SAM chain length increased the XPS C/Au atomic ratio increased due to an increased number of carbon atoms per molecule in the overlayer and an increased attenuation of the Au substrate signal. For the C16 COOH-SAMs, as the size of AuNPs decreased the XPS C/Au atomic ratio and the apparent SAM thickness increased due to the increased curvature of the smaller AuNPs. The C16 COOH-SAMs on the flat Au had the lowest XPS C/Au atomic ratio and apparent SAM thickness of any C16 COOH-SAM covered Au surface. The effective take-off angles of the COOH-SAMs were also calculated by comparing the apparent thickness of COOH-SAMs with literature values. The effective take-off angle for C16 COOH-SAM on 14nm, 25nm and 40nm diameter AuNPs and flat Au were found to be 57°, 53°, 51° and 39°, respectively, for data acquired in a mode that collects a wide range of photoelectron take-off angles. The effective take-off angle for C16 COOH-SAM on 14nm AuNP and flat Au decreased to 52° and 0°, respectively, for data acquired in a mode that collects a narrow range of photoelectron take-off angles. The ToF-SIMS results showed similar changes in surface chemistry with COOH-SAM chain length and AuNP size. For example, the ratio of the sum of the C(1-4)H(x)O(y) positive ion intensities to the sum of the Au-containing positive ions intensities increased with decreasing AuNP size and increasing COOH-SAM chain length. Fourier transform IR spectroscopy in the attenuated total reflectance mode (FTIR-ATR) was used to characterize the crystallinity of the COOH-SAMs. The CH(2) stretching frequencies decreased with increasing COOH-SAM chain length on flat Au. The C16 COOH-SAM on the 14nm AuNPs exhibited a crystalline-like CH(2) stretching frequency. The size, size distribution, shapes and solution stability of AuNPs were investigated with transmission electron microscopy (TEM) and UV/VIS spectroscopy. As the average diameter of the AuNPs decreased the size distribution became narrower and the shape became more spherical.

Dataset Information

Characterization of self-assembled silver nanoparticle ink based on nanoemulsion method.

Publications

Characterization of self-assembled silver nanoparticle ink based on nanoemulsion method.

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