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Bi3+ and Eu3+ Activated Luminescent Behaviors in Non-Stoichiometric LaO0.65F1.7 Structure.


ABSTRACT: Optical materials composed of La1-p-qBipEuqO0.65F1.7 (p = 0.001-0.05, q = 0-0.1) were prepared via a solid-state reaction using La(Bi,Eu)2O3 and NH4F precursors at 1050 °C for two hours. X-ray diffraction patterns of the phosphors were obtained permitting the calculation of unit-cell parameters. The two La3+ cation sites were clearly distinguished by exploiting the photoluminescence excitation and emission spectra through Bi3+ and Eu3+ transitions in the non-stoichiometric host lattice. Energy transfer from Bi3+ to Eu3+ upon excitation with 286 nm radiation and its mechanism in the Bi3+- and Eu3+-doped host structures is discussed. The desired Commission Internationale de l'Eclairage values, including emissions in blue-green, white, and red wavelength regions, were obtained from the Bi3+- and Eu3+-doped LaO0.65F1.7 phosphors.

SUBMITTER: Yang S 

PROVIDER: S-EPMC7287885 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature

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Bi<sup>3+</sup> and Eu<sup>3+</sup> Activated Luminescent Behaviors in Non-Stoichiometric LaO<sub>0.65</sub>F<sub>1.7</sub> Structure.

Yang Sungjun S   Park Sangmoon S  

Materials (Basel, Switzerland) 20200519 10


Optical materials composed of La<sub>1-</sub><i><sub>p</sub></i><sub>-</sub><i><sub>q</sub></i>Bi<i><sub>p</sub></i>Eu<i><sub>q</sub></i>O<sub>0.65</sub>F<sub>1.7</sub> (<i>p</i> = 0.001-0.05, <i>q</i> = 0-0.1) were prepared via a solid-state reaction using La(Bi,Eu)<sub>2</sub>O<sub>3</sub> and NH<sub>4</sub>F precursors at 1050 °C for two hours. X-ray diffraction patterns of the phosphors were obtained permitting the calculation of unit-cell parameters. The two La<sup>3+</sup> cation sites wer  ...[more]

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