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Alkalinity and Its Consequences for the Performance of Steel-Reinforced Geopolymer Materials.

ABSTRACT: This paper investigates the development of the alkalinity and its impact on carbon steel reinforcement embedded in alkali-activated fly ashes (AAFA) and alkali-activated fly ashes with ten percentage mass (wt%) of blast furnace slag (AAFAS)-based materials (geopolymer-GP). The pH analysis of eluates indicates a remarkable decrease of alkalinity in AAFA and AAFAS in the first hours of the geopolymerization process. Phenolphthalein solution and pore solution tests on concretes also show a sharp decrease of alkalinity with increased Ca content in the binder due to carbonation. Micro X-ray computer tomography (µXCT) and electrochemical techniques indicate that the changed pH in the GP systems was accompanied by a decrease in the corrosion rates of steel reinforcement when compared to ordinary Portland cement (OPC) systems. In contrast to calcite and vaterite, which were detected in OPC and AAFAS after a carbonation process, only sodium carbonate natron was determined at lower levels in AAFA by X-ray diffraction (XRD).

SUBMITTER: Koenig A

PROVIDER: S-EPMC7287886 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature

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Alkalinity and Its Consequences for the Performance of Steel-Reinforced Geopolymer Materials.

Koenig Andreas A Mahmoud Hitham H Baehre Oliver O Dehn Frank F

Molecules (Basel, Switzerland) 20200519 10

This paper investigates the development of the alkalinity and its impact on carbon steel reinforcement embedded in alkali-activated fly ashes (AAFA) and alkali-activated fly ashes with ten percentage mass (wt%) of blast furnace slag (AAFAS)-based materials (geopolymer-GP). The pH analysis of eluates indicates a remarkable decrease of alkalinity in AAFA and AAFAS in the first hours of the geopolymerization process. Phenolphthalein solution and pore solution tests on concretes also show a sharp de ...[more]

PMID: 32438581

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Project description:To promote the engineering application of recycled aggregate for concrete production with good adaptability and economic efficiency, this paper performed a campaign to investigate the flexural performance of steel fiber reinforced composite-recycled aggregate concrete (SFR-CRAC) beams matched with 500 MPa longitudinal rebars. The composite-recycled aggregate has features of the full use recycled fine aggregate and small particle recycled coarse aggregate, and the continuous grading of coarse aggregate ensured by admixing the large particle natural aggregate about 35% to 45% in mass of total coarse aggregate. The properties of SFR-CRAC have been comprehensively improved by using steel fibers. With a varying volume fraction of steel fiber from 0% to 2.0%, 10 beam specimens were produced. The flexural behaviors of the beams during the complete loading procedure were experimentally studied under a four-point bending test. Of which the concrete strain at mid-span section, the appearance of cracks, the crack distribution and crack width, the mid-span deflection, the tensile strain of longitudinal rebars, and the failure patterns of the beams were measured in detail. Results indicated that the assumption of plane cross-section held true approximately, the 500 MPa longitudinal rebars worked at a high stress level within the limit width of cracks on reinforced SFR-CRAC beams at the normal serviceability, and the typical failure occurred with the yield of 500 MPa longitudinal rebars followed by the crushed SFR-CRAC in compression. The cracking resistance, the flexural capacity, and the flexural ductility of the beams increased with the volume fraction of steel fiber, while the crack width and mid-span deflection obviously decreased. Finally, by linking to those for conventional reinforced concrete beams, formulas are suggested for predicting the cracking moment, crack width, and flexural stiffness at normal serviceability, and the ultimate moment at bearing capacity of reinforced SFR-CRAC beams.

Dataset Information

Alkalinity and Its Consequences for the Performance of Steel-Reinforced Geopolymer Materials.

Publications

Alkalinity and Its Consequences for the Performance of Steel-Reinforced Geopolymer Materials.

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