Dataset Information

Uptake of Methylene Blue from Aqueous Solution by Naturally Grown Daedalea africana and Phellinus adamantinus Fungi.

ABSTRACT: Herein, Daedalea africana and Phellinus adamantinus were evaluated for the uptake of the methylene blue (MB) dye. Various factors such as pH range, time of exposure, dye concentration, adsorbed quantity, etc. have been studied for the uptake. Adsorption isotherms investigated in this study include the Langmuir and Freundlich isotherms. The Langmuir isotherm has been long known to be the best fit in the process of adsorption. The maximum monolayer adsorption capacity for D. africana was reported to be 0.5210 mol/kg, and it is 1.8387 mol/kg for P. adamantinus at 298 K. The n values 0.8748 and 0.9524 obtained indicate that the dye is favorably adsorbed on both adsorbents. Kinetics data analysis has shown that methylene blue adsorbed on the fungus showed pseudo-second-order chemisorption and film as well as intra particle diffusion. These results reveal that the abovementioned fungi can be used as good sources for the uptake of the MB dye.

SUBMITTER: Sintakindi A

PROVIDER: S-EPMC7288564 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature

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Uptake of Methylene Blue from Aqueous Solution by Naturally Grown Daedalea africana and Phellinus adamantinus Fungi.

Sintakindi Aneeta A Ankamwar Balaprasad B

ACS omega 20200527 22

Herein, Daedalea africana and Phellinus adamantinus were evaluated for the uptake of the methylene blue (MB) dye. Various factors such as pH range, time of exposure, dye concentration, adsorbed quantity, etc. have been studied for the uptake. Adsorption isotherms investigated in this study include the Langmuir and Freundlich isotherms. The Langmuir isotherm has been long known to be the best fit in the process of adsorption. The maximum monolayer adsorption capacity for D. afric ...[more]

PMID: 32548474

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Project description:Microporous- and mesoporous-activated carbons were produced from longan seed biomass through physical activation with CO2 under the same activation conditions of time and temperature. The specially prepared mesoporous carbon showed the maximum porous properties with the specific surface area of 1773 m2/g and mesopore volume of 0.474 cm3/g which accounts for 44.1% of the total pore volume. These activated carbons were utilized as porous adsorbents for the removal of methylene blue (MB) from an aqueous solution and their effectiveness was evaluated for both the adsorption kinetics and capacity. The adsorption kinetic data of MB were analyzed by the pseudo-first-order model, the pseudo-second-order model, and the pore-diffusion model equations. It was found that the adsorption kinetic behavior for all carbons tested was best described by the pseudo-second-order model. The effective pore diffusivity (De) derived from the pore-diffusion model had the values of 4.657 × 10-7-6.014 × 10-7 cm2/s and 4.668 × 10-7-19.920 × 10-7 cm2/s for the microporous- and mesoporous-activated carbons, respectively. Three well-known adsorption models, namely the Langmuir, Freundlich and Redlich-Peterson equations were tested with the experimental MB adsorption isotherms, and the results showed that the Redlich-Peterson model provided the overall best fitting of the isotherm data. In addition, the maximum capacity for MB adsorption of 1000 mg/g was achieved with the mesoporous carbon having the largest surface area and pore volume. The initial pH of MB solution had virtually no effect on the adsorption capacity and removal efficiency of the methylene blue dye. Increasing temperature over the range from 35 to 55 °C increased the adsorption of methylene blue, presumably caused by the increase in the diffusion rate of methylene blue to the adsorption sites that could promote the interaction frequency between the adsorbent surface and the adsorbate molecules. Overall, the high surface area mesoporous carbon was superior to the microporous carbon in view of the adsorption kinetics and capacity, when both carbons were used for the removal of MB from an aqueous solution.

Dataset Information

Uptake of Methylene Blue from Aqueous Solution by Naturally Grown Daedalea africana and Phellinus adamantinus Fungi.

Publications

Uptake of Methylene Blue from Aqueous Solution by Naturally Grown <i>Daedalea africana</i> and <i>Phellinus adamantinus</i> Fungi.

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