Ontology highlight
ABSTRACT:
SUBMITTER: Moock D
PROVIDER: S-EPMC7295364 | biostudies-literature | 2020 Jun
REPOSITORIES: biostudies-literature
ACS catalysis 20200505 11
Recently, chemoselective methods for the hydrogenation of fluorinated, silylated, and borylated arenes have been developed providing direct access to previously unattainable, valuable products. Herein, a comprehensive study on the employed rhodium-cyclic (alkyl)(amino)carbene (CAAC) catalyst precursor is disclosed. Mechanistic experiments, kinetic studies, and surface-spectroscopic methods revealed supported rhodium(0) nanoparticles (NP) as the active catalytic species. Further studies suggest t ...[more]