Establishing magneto-structural relationships in the solid solutions of the skyrmion hosting family of materials: GaV₄S_8-ySe_y.

ABSTRACT: The GaV₄S_8-ySe_y (y = 0 to 8) family of materials have been synthesized in both polycrystalline and single crystal form, and their structural and magnetic properties thoroughly investigated. Each of these materials crystallizes in the F[Formula: see text][Formula: see text]3m space group at ambient temperature. However, in contrast to the end members GaV₄S₈ and GaV₄Se₈, that undergo a structural transition to the R3m space group at 42 and 41 K respectively, the solid solutions (y = 1 to 7) retain cubic symmetry down to 1.5 K. In zero applied field the end members of the family order ferromagnetically at 13 K (GaV₄S₈) and 18 K (GaV₄Se₈), while the intermediate compounds ex

SUBMITTER: Stefancic A 

PROVIDER: S-EPMC7299962 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature