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ABSTRACT:
SUBMITTER: Temperton RH
PROVIDER: S-EPMC7307919 | biostudies-literature | 2020 Feb
REPOSITORIES: biostudies-literature
Temperton Robert H RH Rosemann Nils W NW Guo Meiyuan M Johansson Niclas N Fredin Lisa A LA Prakash Om O Wärnmark Kenneth K Handrup Karsten K Uhlig Jens J Schnadt Joachim J Persson Petter P
The journal of physical chemistry. A 20200218 8
We present the first experimental study of the frontier orbitals in an ultrathin film of the novel hexa-carbene photosensitizer [Fe(btz)<sub>3</sub>]<sup>3+</sup>, where btz is 3,3'-dimethyl-1,1'-bis(<i>p</i>-tolyl)-4,4'-bis(1,2,3-triazol-5-ylidene). Resonant photoelectron spectroscopy (RPES) was used to probe the electronic structure of films where the molecular and oxidative integrities had been confirmed with optical and X-ray spectroscopies. In combination with density functional theory calc ...[more]