Dataset Information

A Cornucopia of Iridium Nitrogen Compounds Produced from Laser-Ablated Iridium Atoms and Dinitrogen.

ABSTRACT: The reaction of laser-ablated iridium atoms with dinitrogen molecules and nitrogen atoms yield several neutral and ionic iridium dinitrogen complexes such as Ir(N2 ), Ir(N2 )+ , Ir(N2 )2 , Ir(N2 )2 - , IrNNIr, as well as the nitrido complexes IrN, Ir(N)2 and IrIrN. These reaction products were deposited in solid neon, argon and nitrogen matrices and characterized by their infrared spectra. Assignments of vibrational bands are supported by ab initio and first principle calculations as well as 14/15 N isotope substitution experiments. The structural and electronic properties of the new dinitrogen and nitrido iridium complexes are discussed. While the formation of the elusive dinitrido complex Ir(N)2 was observed in a subsequent reaction of IrN with N atoms within the cryogenic solid matrices, the threefold coordinated iridium trinitride Ir(N)3 could not be observed so far.

SUBMITTER: Stuker T

PROVIDER: S-EPMC7317413 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

A Cornucopia of Iridium Nitrogen Compounds Produced from Laser-Ablated Iridium Atoms and Dinitrogen.

Stüker Tony T Beckers Helmut H Riedel Sebastian S

Chemistry (Weinheim an der Bergstrasse, Germany) 20200430 33

The reaction of laser-ablated iridium atoms with dinitrogen molecules and nitrogen atoms yield several neutral and ionic iridium dinitrogen complexes such as Ir(N2 ), Ir(N2 )+ , Ir(N2 )2 , Ir(N2 )2 - , IrNNIr, as well as the nitrido complexes IrN, Ir(N)2 and IrIrN. These reaction products were deposited in solid neon, argon and nitrogen matrices and characterized by their infrared spectra. Assignme ...[more]

PMID: 31951304

Similar Datasets

Project description:Osseointegration, the ability for an implant to be anchored in bone tissue with direct bone-implant contact and allowing for continuous adaptive remodelling, is clinically used in different reconstructive fields, such as dentistry, orthopedics and otology. The latter uses a bone conducting sound processor connected to a skin-penetrating abutment that is mounted on a titanium implant placed in the temporal bone, thereby acting as a path for transmission of the vibrations generated by the sound processor. The success of the treatment relies on bone healing and osseointegration, which could be improved by surface modifications. The aim of this study was to evaluate the long-term osseointegration in a sheep skull model and compare a laser-ablated implant surface with a machined implant. Commercially available 4 mm titanium implants, either with a machined (Wide Ponto) or a laser-ablated surface (Ponto BHX, Oticon Medical, Sweden), were used in the current study. The surfaces were evaluated by scanning electron microscopy. The implantation was performed with a full soft tissue flap and the osteotomy was prepared using the MIPS drill kit (Oticon Medical, Sweden) prior to installation of the implants in the frontal bone of eight female sheep. After five months, biopsies including the implant and surrounding bone tissue obtained, processed and analysed using histology, histomorphometry, scanning electron microscopy and Raman spectroscopy. The animals healed well, without signs of adverse events. Histomorphometry showed a large amount of bone tissue around both implant types, with 75% of the threaded area occupied by bone for both implant types. A large amount of bone-implant contact was observed for both implant types, with 67%-71% of the surface covered by bone. Both implant types were surrounded by mature remodelled lamellar bone with high mineral content, corroborating the histological observations. The current results show that the laser-ablated surface induces healing similar to the well-known clinically used machined surface in ovine cranial bone. In conclusion, the present long-term experimental results indicate that a laser-ablated implant performs equally well as a clinically used implant with a machined surface. This, together with previously reported, improved early biomechanical anchorage, suggests future, safe and efficient clinical potential.

Dataset Information

A Cornucopia of Iridium Nitrogen Compounds Produced from Laser-Ablated Iridium Atoms and Dinitrogen.

Publications

A Cornucopia of Iridium Nitrogen Compounds Produced from Laser-Ablated Iridium Atoms and Dinitrogen.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets