Co-Crosslinked Water-Soluble Biopolymers as a Binder for High-Voltage LiNi0.5 Mn1.5 O4 |Graphite Lithium-Ion Full Cells.

ABSTRACT: The use of water-soluble, abundant biopolymers as binders for lithium-ion positive electrodes is explored because it represents a great step forward towards environmentally benign battery processing. However, to date, most studies that employ, for instance, carboxymethyl cellulose (CMC) as a binder have focused on rather low electrode areal loadings with limited relevance for industrial needs. This study concerns the use of natural guar gum (GG) as a binding agent for cobalt-free, high-voltage LiNi0.5 Mn1.5 O4 (LNMO), which realizes electrodes with substantially increased areal loadings, low binder content, and greatly enhanced cycling stability. Co-crosslinking GG through citric acid with CMC allows for an enhanced rate capability and essentially maintains the beneficial impact of using GG as a binder rather than CMC only. Lithium-ion full cells based on water-processed LNMO and graphite electrodes provide a remarkably high cycling stability with 80?% capacity retention after 1000?cycles at 1?C.

SUBMITTER: Kuenzel M 

PROVIDER: S-EPMC7318297 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature