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A HF Loaded Lewis-Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions.

ABSTRACT: The very strong Lewis acid aluminium chlorofluoride (ACF) was loaded with anhydrous HF. The interaction between the surface of the catalyst and HF was investigated using a variety of characterization methods, which revealed the formation of polyfluorides. Moreover, the reactivity of the HF-loaded ACF towards the hydrofluorination of alkynes was studied.

SUBMITTER: Kervarec MC

PROVIDER: S-EPMC7318592 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature

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A HF Loaded Lewis-Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions.

Kervarec Maëva-Charlotte MC Kemnitz Erhard E Scholz Gudrun G Rudić Svemir S Braun Thomas T Jäger Christian C Michalchuk Adam A L AAL Emmerling Franziska F

Chemistry (Weinheim an der Bergstrasse, Germany) 20200526 32

The very strong Lewis acid aluminium chlorofluoride (ACF) was loaded with anhydrous HF. The interaction between the surface of the catalyst and HF was investigated using a variety of characterization methods, which revealed the formation of polyfluorides. Moreover, the reactivity of the HF-loaded ACF towards the hydrofluorination of alkynes was studied. ...[more]

PMID: 32315479

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