Dataset Information

Photoluminescent, Ferromagnetic, and Hydrophobic Sponges for Oil-Water Separation.

ABSTRACT: To find a facile way to produce a hydrophobic sponge that can effectively absorb oils is urgent to resolve the environmental pollution and ecological disaster caused by oil spillage. Here, alkylated carbon dots (C dots) were prepared from pyrolysis of a mixture of dodecylamine and citric acid followed by purification through silica gel column chromatography. Polyurethane sponge was modified by alkylated C dots by a simple dip-coating method, which endows the photoluminescent and hydrophobic sponge with good absorption capacities for various oils and nonpolar organic solvents with high recyclability. The water contact angle of the modified sponge can reach 138.8°. Interestingly, the sponge enables visual absorption under UV irradiation in the dark, which has not been achieved by other carbon-based adsorbents. The sponge was further made ferromagnetic by introducing alkylated Fe3O4 nanoparticles into its structure, which allowed controllable oil-water separation.

SUBMITTER: Yin K

PROVIDER: S-EPMC7330909 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature

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Photoluminescent, Ferromagnetic, and Hydrophobic Sponges for Oil-Water Separation.

Yin Keyang K Lu Dandan D Sun Bangping B Kalwarczyk Tomasz T Hołyst Robert R Hao Junying J Li Hongguang H Hao Jingcheng J

ACS omega 20200619 25

To find a facile way to produce a hydrophobic sponge that can effectively absorb oils is urgent to resolve the environmental pollution and ecological disaster caused by oil spillage. Here, alkylated carbon dots (C dots) were prepared from pyrolysis of a mixture of dodecylamine and citric acid followed by purification through silica gel column chromatography. Polyurethane sponge was modified by alkylated C dots by a simple dip-coating method, which endows the photoluminescent and hydrophobic spon ...[more]

PMID: 32637780

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Project description:Designing and synthesizing materials with smart hydrophobicity against an external magnetic field for efficient oil/water separation is of great importance due to the increasing problems caused by oil pollution. Here, the nanocomposites were fabricated based on graphene and different iron oxides exhibit smart hydrophobicity against an external magnetic field and they are in powder form eliminating the requirement for a substrate employing a facile and echo friendly method. The results prove that autoclaving of graphene leads to its ferromagnetic property; then it is attached to iron oxides by magnetic attraction and a nanocomposite is produced. The magnetic property of the resulting nanocomposite is higher than the magnetic property of its individual components. In addition, following nanocomposite formation, its hydrophobicity and surface area also change. FESEM images were taken from the nanocomposites to study their surface morphology, and EDS-MAP analysis to observe the elemental distribution uniformity of the nanocomposites. Also, to measure the surface area and pore size, BET analysis has been performed on pure materials and graphene-black iron oxide nanocomposite (graphene@black iron oxide). The results show that the specific surface area of black iron oxide increases after being composited with graphene dispersed at 5000 rpm. Indeed, graphene forms a composite by binding to iron oxide, and therefore, its specific surface area increases compared to iron oxide and graphene alone. These results show an increase in oil sorption and better separation of oil from water by the prepared nanocomposite. Also, to measure the magnetic properties of pure materials, graphene@black iron oxide, and ferromagnetic graphene at 3000 and 5000 rpm, the Vibrating Sample Magnetometer analysis has been performed. The results have proven that the nanocomposite powder prepared by a simple method obtained from cost-effective and available materials is hydrophobic and becomes more hydrophobic by applying an external magnetic field. Due to the ease with which oil can be readily removed from the nanocomposite by eliminating the external magnetic field, this nanocomposite is an excellent choice for the separation of oil from water.

Dataset Information

Photoluminescent, Ferromagnetic, and Hydrophobic Sponges for Oil-Water Separation.

Publications

Photoluminescent, Ferromagnetic, and Hydrophobic Sponges for Oil-Water Separation.

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