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Valorisation of crude glycerol to value-added products: Perspectives of process technology, economics and environmental issues.

ABSTRACT: The enormous production of glycerol, a waste stream from biodiesel industries, as a low-value product has been causing a threat to both the environment and the economy. Therefore, it needs to be transformed effectively and efficiently into valued products for contributing positively towards the biodiesel economy. It can either be converted directly into competent chemicals or can be used as a feedstock/precursor for deriving valuable derivatives. In this review article, a technical evaluation has been stirred up, various factors and technologies used for producing value-added products from crude glycerol, Environmental and economic aspects of different conversion routes, cost factors and challenges of integration of the different routes for biorefinery have been reviewed and elaborated. There are tremendous environmental benefits in the conversion of crude glycerol via the biochemical route, the product and residue become eco-friendly. However, chemical conversions are faster processes, and economically viable if environmental aspects are partially ignored.

SUBMITTER: Kaur J

PROVIDER: S-EPMC7334398 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

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Valorisation of crude glycerol to value-added products: Perspectives of process technology, economics and environmental issues.

Kaur Jaspreet J Sarma Anil Kumar AK Jha Mithilesh Kumar MK Gera Poonam P

Biotechnology reports (Amsterdam, Netherlands) 20200612

The enormous production of glycerol, a waste stream from biodiesel industries, as a low-value product has been causing a threat to both the environment and the economy. Therefore, it needs to be transformed effectively and efficiently into valued products for contributing positively towards the biodiesel economy. It can either be converted directly into competent chemicals or can be used as a feedstock/precursor for deriving valuable derivatives. In this review article, a technical evaluation ha ...[more]

PMID: 32642454

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Project description:Crude glycerol (CG) and glycerol pitch (GP) are highly alkaline residues from biodiesel and oleochemical plants, respectively, and have organic content which incurs high disposal cost and poses an environmental threat. Characterization of these residues for composition and properties could provide insight into their quality for proper disposal and can help the biodiesel industry to adopt more sustainable practices, such as reducing waste and improving the efficiency of the production process, hence minimizing the impact of the biodiesel supply chain to the environment. These data also allow the identification and exploration of new ways for their utilization and transformation into highly value-added products. In this study, we evaluated four CG samples (B, C, D, and E) and two GP samples (F and G) obtained from Malaysian palm oil refineries, and the results were compared with pure glycerol (A). Spectroscopic analysis was performed using FTIR, 1H-, and 13C-NMR. All samples had similar density to A (1.26 g/cm3), except for F (1.31 g/cm3), while the density for E and G could not be determined due to their physical states. The pH and viscosity largely varied in the range of 7.26–11.89 and 43–225 cSt, respectively. The glycerol content of CG (B, C, D, and E) was high and consistent (81.7–87.3%) whereas GP F and G had 71.5 and 63.9% glycerol content, respectively. Major contaminants in CG and GP were water and matter organic non-glycerol (MONG), respectively. The water, ash, soap, and salt content were considerably low, which varied from 3.4 to 14.1%, 3.9 to 13.0%, 0.1 to 5.7%, and 4.1 to 9.2% respectively. Thermal analysis of CG and GP exhibited four phases of decomposition attributed to the impurities compared to the single phase in A. All samples had calorific values lower than A (18.1 MJ/kg) between 9.0 and 17.7 MJ/kg. Based on the results, CG and GP have high glycerol content which reveals their potential to be used as feedstock in bioconversion and chemical or thermal treatment while impurities may be removed by pre-treatment if required. As palm oil is one of the main feedstocks for the oleochemical industry, this work underlines the importance of characterization of the residue generated to provide additional data and information on palm-based agricultural industry wastes, minimize the impact of palm oil supply chain on the environment, and explore its potential usage for value-addition. Supplementary Information The online version contains supplementary material available at 10.1007/s13399-023-04003-4.

Project description:BackgroundEscalating demands upon the National Institute for Health and Care Excellence's (NICE's) Single Technology Appraisal (STA) programme require a 2.5-times increase upon 2015 capacity by 2020. This additional strain on committee resources threatens to compromise the rigour of the STA process. In 2018, NICE introduced changes to the appraisal process, aiming to expedite final decisions, including consultation opportunities prior to the company's evidence submission, a 'Technical Engagement' stage prior to the first committee meeting, and powers for committee chairs to recommend technologies without a second formal meeting.ObjectiveThis study reviews recent STAs and aims to understand why appraisals require multiple meetings, and whether recent reforms can address the underlying issues.MethodsNICE STAs published between January 2010 and January 2018 were reviewed, excluding updates or re-considerations. Data on cost, clinical, and decision-making outcomes from 146 appraisals were extracted and analysed thematically.ResultsDrugs for advanced cancers were least likely to be recommended (28/43 [65.1%] vs 71/74 [96%] for non-cancer) and took longer (2.36 meetings for a final decision vs 1.97 for non-cancer). The academic review increased upon the company's base-case incremental cost-effectiveness ratio by a median of 32.7%. Eighty-four technologies (57.5%) received a negative preliminary recommendation, deferring a final decision by an average of 142 days. Of these, 85.1% were not considered cost-effective. Uncertainty in economic (34.3%) and clinical (22.3%) data also prevented a positive decision. The majority (72.6% [61/84]) of negative preliminary decisions were overturned following further committee discussion; important considerations were Patient Access Schemes, decision optimisation, and the Cancer Drugs Fund.ConclusionsValue considerations are the primary driver of negative preliminary recommendations. It is unclear if new opportunities for additional interaction between NICE, review groups, and manufacturers will meaningfully improve the efficiency of the appraisal process, particularly given the proportion of technologies requiring further committee discussion for decision optimisation or admission into the CDF.

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Valorisation of crude glycerol to value-added products: Perspectives of process technology, economics and environmental issues.

Publications

Valorisation of crude glycerol to value-added products: Perspectives of process technology, economics and environmental issues.

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