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Crystal structure, Hirshfeld surface analysis and DFT studies of (E)-4-methyl-2-{[(4-methyl-phen-yl)imino]-meth-yl}phenol.


ABSTRACT: In the title compound, C15H15NO, the configuration of the C=N bond of the Schiff base is E, and an intra-molecular O-H?N hydrogen bond is observed, forming an intra-molecular S(6) ring motif. The phenol ring is inclined by 45.73?(2)° from the plane of the aniline ring. In the crystal, mol-ecules are linked along the b axis by O-H?N and C-H?O hydrogen bonds, forming polymeric chains. The Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the packing arrangement are from H?H (56.9%) and H?C/C?H (31.2%) inter-actions. The density functional theory (DFT) optimized structure at the B3LYP/ 6-311?G(d,p) level is compared with the experimentally determined mol-ecular structure, and the HOMO-LUMO energy gap is provided. The crystal studied was refined as an inversion twin.

SUBMITTER: Yagci NK 

PROVIDER: S-EPMC7336782 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature

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Crystal structure, Hirshfeld surface analysis and DFT studies of (<i>E</i>)-4-methyl-2-{[(4-methyl-phen-yl)imino]-meth-yl}phenol.

Yagci Nermin Kahveci NK   Faizi Md Serajul Haque MSH   Aydin Alev Sema AS   Dege Necmi N   Dogan Onur Erman OE   Agar Erbil E   Mashrai Ashraf A  

Acta crystallographica. Section E, Crystallographic communications 20200616 Pt 7


In the title compound, C<sub>15</sub>H<sub>15</sub>NO, the configuration of the C=N bond of the Schiff base is <i>E</i>, and an intra-molecular O-H⋯N hydrogen bond is observed, forming an intra-molecular <i>S</i>(6) ring motif. The phenol ring is inclined by 45.73 (2)° from the plane of the aniline ring. In the crystal, mol-ecules are linked along the <i>b</i> axis by O-H⋯N and C-H⋯O hydrogen bonds, forming polymeric chains. The Hirshfeld surface analysis of the crystal structure indicates that  ...[more]

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