Broadband infrared LEDs based on europium-to-terbium charge transfer luminescence.

ABSTRACT: Efficient broadband infrared (IR) light-emitting diodes (LEDs) are needed for emerging applications that exploit near-IR spectroscopy, ranging from hand-held electronics to medicine. Here we report broadband IR luminescence, cooperatively originating from Eu²⁺ and Tb³⁺ dopants in CaS. This peculiar emission overlaps with the red Eu²⁺ emission, ranges up to 1200 nm (full-width-at-half-maximum of 195 nm) and is efficiently excited with visible light. Experimental evidence for metal-to-metal charge transfer (MMCT) luminescence is collected, comprising data from luminescence spectroscopy, microscopy and X-ray spectroscopy. State-of-the-art multiconfigurational ab initio calculations attribute the IR emission to the radiative decay of a metastable MMCT state of a Eu²⁺-Tb³⁺ pair. The calculations explain why no MMCT emission is found in the similar compound SrS:Eu,Tb and are used to anticipate how to fine-tune the characteristics of the MMCT luminescence. Finally, a near-IR LED for versatile spectroscopic use is manufactured based on the MMCT emission.

SUBMITTER: Joos JJ 

PROVIDER: S-EPMC7371692 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature