Dataset Information

Carboxymethylcellulose Mediates the Transport of Carbon Nanotube-Magnetite Nanohybrid Aggregates in Water-Saturated Porous Media.

ABSTRACT: Carbon-metal oxide nanohybrids (NHs) are increasingly recognized as the next-generation, promising group of nanomaterials for solving emerging environmental issues and challenges. This research, for the first time, systematically explored the transport and retention of carbon nanotube-magnetite (CNT-Fe3O4) NH aggregates in water-saturated porous media under environmentally relevant conditions. A macromolecule modifier, carboxymethylcellulose (CMC), was employed to stabilize the NHs. Our results show that transport of the magnetic CNT-Fe3O4 NHs was lower than that of nonmagnetic CNT due to larger hydrodynamic sizes of NHs (induced by magnetic attraction) and size-dependent retention in porous media. Classical Derjaguin-Landau-Verwey-Overbeek (DLVO) theory can explain the mobility of NHs under varying experimental conditions. However, in contrast with colloid filtration theory, a novel transport feature-an initial lower and a following sharp-higher peaks occurred frequently in the NHs' breakthrough curves. The magnitude and location of both transport peaks varied with different experimental conditions, due to the interplay between variability of fluid viscosity and size-selective retention of the NHs. Promisingly, the estimated maximum transport distance of NHs ranged between ?0.38 and 46 m, supporting the feasibility of employing the magnetically recyclable CNT-Fe3O4 NHs for in situ nanoremediation of contaminated soil, aquifer, and groundwater.

SUBMITTER: Wang D

PROVIDER: S-EPMC7375327 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature

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Carboxymethylcellulose Mediates the Transport of Carbon Nanotube-Magnetite Nanohybrid Aggregates in Water-Saturated Porous Media.

Wang Dengjun D Park Chang Min CM Masud Arvid A Aich Nirupam N Su Chunming C

Environmental science & technology 20171025 21

Carbon-metal oxide nanohybrids (NHs) are increasingly recognized as the next-generation, promising group of nanomaterials for solving emerging environmental issues and challenges. This research, for the first time, systematically explored the transport and retention of carbon nanotube-magnetite (CNT-Fe<sub>3</sub>O<sub>4</sub>) NH aggregates in water-saturated porous media under environmentally relevant conditions. A macromolecule modifier, carboxymethylcellulose (CMC), was employed to stabilize ...[more]

PMID: 29037033

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Project description:Little is known about the fate and transport of the "new-horizon" multifunctional nanohybrids in the environment. Saturated sand-packed column experiments ( n = 66) were therefore performed to investigate the transport and retention of reduced graphene oxide (RGO)-metal oxide (Fe3O4, TiO2, and ZnO) nanohybrids under environmentally relevant conditions (mono- and divalent electrolytes and natural organic matter). Classical colloid science principles (Derjaguin-Landau-Verwey-Overbeek (DLVO) theory and colloid filtration theory (CFT)) and mathematical models based on the one-dimensional convection-dispersion equation were employed to describe and predict the mobility of RGO-Fe3O4, RGO-TiO2, and RGO-ZnO nanohybrids in porous media. Results indicate that the mobility of the three nanohybrids under varying experimental conditions is overall explainable by DLVO theory and CFT. Numerical simulations suggest that the one-site kinetic retention model (OSKRM) considering both time- and depth-dependent retention accurately approximated the breakthrough curves (BTCs) and retention profiles (RPs) of the nanohybrids concurrently; whereas, others (e.g., two-site retention model) failed to capture the BTCs and/or RPs. This is primarily because blocking BTCs and exponential/hyperexponential/uniform RPs occurred, which is within the framework of OSKRM featuring time- (for kinetic Langmuirian blocking) and depth-dependent (for exponential/hyperexponential/uniform) retention kinetics. Employing fitted parameters (maximum solid-phase retention capacity: Smax = 0.0406-3.06 cm3/g; and first-order attachment rate coefficient: ka = 0.133-20.6 min-1) extracted from the OSKRM and environmentally representative physical variables (flow velocity (0.00441-4.41 cm/min), porosity (0.24-0.54), and grain size (210-810 μm)) as initial input conditions, the long-distance transport scenarios (in 500 cm long sand columns) of the three nanohybrids were predicted via forward simulation. Our findings address the existing knowledge gap regarding the impact of physicochemical factors on the transport of the next-generation, multifunctional RGO-metal oxide nanohybrids in the subsurface.

Dataset Information

Carboxymethylcellulose Mediates the Transport of Carbon Nanotube-Magnetite Nanohybrid Aggregates in Water-Saturated Porous Media.

Publications

Carboxymethylcellulose Mediates the Transport of Carbon Nanotube-Magnetite Nanohybrid Aggregates in Water-Saturated Porous Media.

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