Ontology highlight
ABSTRACT:
SUBMITTER: Baumgardner DF
PROVIDER: S-EPMC7386000 | biostudies-literature | 2020 Jan
REPOSITORIES: biostudies-literature
Baumgardner Douglas F DF Parks Wyatt E WE Gilbertson John D JD
Dalton transactions (Cambridge, England : 2003) 20200107 4
Metalloenzymes catalyze many important reactions by managing the proton and electron flux at the enzyme active site. The motifs utilized to facilitate these transformations include hemilabile, redox-active, and so called proton responsive sites. Given the importance of incorporating and understanding these motifs in the area of coordination chemistry and catalysis, we highlight recent milestones in the field. Work incorporating the triad of hemilability, redox-activity, and proton responsivity i ...[more]