Unknown

Dataset Information

0

Highly Porous MIL-100(Fe) for the Hydrogen Evolution Reaction (HER) in Acidic and Basic Media.

ABSTRACT: The present study reports the synthesis of a porous Fe-based MOF named MIL-100(Fe) by a modified hydrothermal method without the HF process. The synthesis gave a high surface area with the specific surface area calculated to be 2551 m2 g-1 and a pore volume of 1.407 cm3 g-1 with an average pore size of 1.103 nm. The synthesized electrocatalyst having a high surface area is demonstrated as an excellent electrocatalyst for the hydrogen evolution reaction investigated in both acidic and alkaline media. As desired, the electrochemical results showed low Tafel slopes (53.59 and 56.65 mV dec-1), high exchange current densities (76.44 and 72.75 mA cm-2), low overpotentials (148.29 and 150.57 mV), and long-term stability in both media, respectively. The high activity is ascribed to the large surface area of the synthesized Fe-based metal-organic framework with porous nature.

SUBMITTER: Nivetha R 

PROVIDER: S-EPMC7408201 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

The present study reports the synthesis of a porous Fe-based MOF named MIL-100(Fe) by a modified hydrothermal method without the HF process. The synthesis gave a high surface area with the specific surface area calculated to be 2551 m<sup>2</sup> g<sup>-1</sup> and a pore volume of 1.407 cm<sup>3</sup> g<sup>-1</sup> with an average pore size of 1.103 nm. The synthesized electrocatalyst having a high surface area is demonstrated as an excellent electrocatalyst for the hydrogen evolution reaction  ...[more]

Similar Datasets

Unknown A novel SERS substrate of MIL-100(Fe)/AgNFs for sensitive detection of ascorbic acid in cellular media.
| S-EPMC9400642 | biostudies-literature
Unknown A bimetallic oxide Fe<sub>1.89</sub>Mo<sub>4.11</sub>O<sub>7</sub> electrocatalyst with highly efficient hydrogen evolution reaction activity in alkaline and acidic media.
| S-EPMC6049016 | biostudies-literature
Unknown Oxygen Evolution Reaction at Microporous Pt Layers: Differentiated Electrochemical Activity between Acidic and Basic Media.
| S-EPMC5684209 | biostudies-literature
Unknown MIL-100(Fe) Sub-Micrometric Capsules as a Dual Drug Delivery System.
| S-EPMC9324886 | biostudies-literature
Unknown Chitosan-coated mesoporous MIL-100(Fe) nanoparticles as improved bio-compatible oral nanocarriers.
| S-EPMC5335263 | biostudies-literature
Unknown Metal-Organic Frameworks of MIL-100(Fe, Cr) and MIL-101(Cr) for Aromatic Amines Adsorption from Aqueous Solutions.
| S-EPMC6832246 | biostudies-literature
Unknown Molybdenum Carbide Nanoparticles Coated into the Graphene Wrapping N-Doped Porous Carbon Microspheres for Highly Efficient Electrocatalytic Hydrogen Evolution Both in Acidic and Alkaline Media.
| S-EPMC5867049 | biostudies-literature
Unknown Electrospun interconnected Fe-N/C nanofiber networks as efficient electrocatalysts for oxygen reduction reaction in acidic media.
| S-EPMC4663764 | biostudies-literature
Unknown Observation of Ag Nanoparticles in/on Ag@MIL-100(Fe) Prepared Through Different Procedures.
| S-EPMC6817505 | biostudies-literature
Unknown Chromium-ruthenium oxide solid solution electrocatalyst for highly efficient oxygen evolution reaction in acidic media.
| S-EPMC6329788 | biostudies-literature