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Residue and Dissipation Kinetics of Metsulfuron-Methyl Herbicide in Soil: A Field Assessment at an Oil Palm Plantation.


ABSTRACT: A field trial experiment was conducted to investigate the degradation of metsulfuron-methyl at two application dosages, 15 g a.i/ha and 30 g a.i/ha, at an oil palm plantation. Soil samples were collected at ?1, 0, 1, 3, 7, 14, and 21 days after treatment (DAT) at the following depths: 0-10, 10-20, 20-30, 30-40, and 40-50 cm. The results showed rapid degradation of metsulfuron-methyl in the soil, with calculated half-life (t½) values ranging from 6.3 and 7.9 days. The rates of degradation of metsulfuron-methyl followed first-order reaction kinetics (R2 = 0.91-0.92). At the spray dosage of 15 g a.i/ha, metsulfuron-methyl residue was detected at up to 20-30 cm soil depth, at 3.56% to 1.78% at 3 and 7 DAT, respectively. Doubling the dosage to 30 g a.i/ha increased the metsulfuron-methyl residue in up to 30-40 cm soil depth at 3, 7, and 14 DAT, with concentrations ranging from 1.90% to 1.74%. These findings suggest that metsulfuron-methyl has a low impact on the accumulation of the residues in the soil at application dosages of 15 g a.i/ha and 30 g a.i/ha, due to rapid degradation, and the half-life was found to be 6.3 to 7.9 days.

SUBMITTER: Maznah Z 

PROVIDER: S-EPMC7408506 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature

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Residue and Dissipation Kinetics of Metsulfuron-Methyl Herbicide in Soil: A Field Assessment at an Oil Palm Plantation.

Maznah Zainol Z   Ismail B Sahid BS   Eng Oii Kok OK  

Biomolecules 20200716 7


A field trial experiment was conducted to investigate the degradation of metsulfuron-methyl at two application dosages, 15 g a.i/ha and 30 g a.i/ha, at an oil palm plantation. Soil samples were collected at ‒1, 0, 1, 3, 7, 14, and 21 days after treatment (DAT) at the following depths: 0-10, 10-20, 20-30, 30-40, and 40-50 cm. The results showed rapid degradation of metsulfuron-methyl in the soil, with calculated half-life (<i>t</i><sub>½</sub>) values ranging from 6.3 and 7.9 days. The rates of d  ...[more]

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