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Deposition of NiO Nanoparticles on Nanosized Zeolite NaY for Production of Biofuel via Hydrogen-Free Deoxygenation.

ABSTRACT: Nickel-based catalysts play an important role in the hydrogen-free deoxygenation for the production of biofuel. The yield and quality of the biofuel are critically affected by the physicochemical properties of NiO supported on nanosized zeolite Y (Y65, crystal size of 65 nm). Therefore, 10 wt% NiO supported on Y65 synthesized by using impregnation (IM) and deposition-precipitation (DP) methods were investigated. It was found that preparation methods have a significant effect on the deoxygenation of triolein. The initial rate of the DP method (14.8 goil·h-1) was 1.5 times higher than that of the IM method (9.6 goil·h-1). The DP-Y65 showed the best deoxygenation performance with a 80.0% conversion and a diesel selectivity of 93.7% at 380 °C within 1 h. The outstanding performance from the DP method was due to the smaller NiO particle size (3.57 ± 0.40 nm), high accessibility (H.F value of 0.084), and a higher Brönsted to Lewis acidity (B/L) ratio (0.29), which has improved the accessibility and deoxygenation ability of the catalyst. The NH4+ released from the decomposition of the urea during the DP process increased the B/L ratio of zeolite NaY. As a result, the pretreatment to convert Na-zeolite to H-zeolite in a conventional zeolite synthesis can be avoided. In this regard, the DP method offers a one-pot synthesis to produce smaller NiO-supported nanosized zeolite NaY with a high B/L ratio, and it managed to produce a higher yield with selectivity towards green diesel via deoxygenation under a hydrogen-free condition.

SUBMITTER: Choo MY

PROVIDER: S-EPMC7412304 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature

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Deposition of NiO Nanoparticles on Nanosized Zeolite NaY for Production of Biofuel via Hydrogen-Free Deoxygenation.

Choo Min-Yee MY Oi Lee Eng LE Daou T Jean TJ Ling Tau Chuan TC Lin Yu-Chuan YC Centi Gabriele G Ng Eng-Poh EP Juan Joon Ching JC

Materials (Basel, Switzerland) 20200711 14

Nickel-based catalysts play an important role in the hydrogen-free deoxygenation for the production of biofuel. The yield and quality of the biofuel are critically affected by the physicochemical properties of NiO supported on nanosized zeolite Y (Y65, crystal size of 65 nm). Therefore, 10 wt% NiO supported on Y65 synthesized by using impregnation (IM) and deposition-precipitation (DP) methods were investigated. It was found that preparation methods have a significant effect on the deoxygenation ...[more]

PMID: 32664579

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Project description:Pure and modified mesoporous TiO2 nanoparticles with different loadings of NiO (3-20.0 wt %) were prepared through the surfactant-assisted sol-gel approach with the use of cetyltrimethylammonium bromide as a template. The optical and structural properties of different samples were examined using N2 adsorption-desorption analysis, energy-dispersive spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, UV-vis spectroscopy, Fourier transform infrared spectroscopy, and photoluminescence (PL) spectroscopy. X-ray diffraction results confirmed the insertion of Ni2+ into the lattice of TiO2, and the crystallite size reduced remarkably after the addition of NiO. The diffuse reflectance spectroscopy spectra displayed obvious red shift in the absorption edges, and new absorption bands appeared in the visible region when NiO was added, which indicates the formation of surface defects and oxygen vacancies. The optical band gap of TiO2 reduced sharply when the contents of NiO were increased. The increase in the surface defects as well as oxygen vacancies were examined using PL spectroscopy. The photocatalytic performance of the as-synthesized samples was investigated over photodegradation of brilliant green (BG) and phenol and hydrogen generation under visible light. 10% NiO/TiO2 exhibited the highest photocatalytic efficiency. The photocatalytic activity was improved due to the creation of a p-n junction at the interface of NiO/TiO2, which efficiently promotes the separation of photogenerated electron/hole pairs and consequently enhances its photodegradation activity. According to the photocatalytic activity results, NiO contents were considered one of the most important factors affecting the photodegradation of BG and phenol and H2 evolution. Also, we discussed the mechanism of photodegradation, mineralization (total organic carbon), and photocatalytic reaction kinetics of BG and phenol.

Dataset Information

Deposition of NiO Nanoparticles on Nanosized Zeolite NaY for Production of Biofuel via Hydrogen-Free Deoxygenation.

Publications

Deposition of NiO Nanoparticles on Nanosized Zeolite NaY for Production of Biofuel via Hydrogen-Free Deoxygenation.

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