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Cr2P2O7 as a Novel Anode Material for Sodium and Lithium Storage.


ABSTRACT: The development of new appropriate anode material with low cost is still main issue for sodium-ion batteries (SIBs) and lithium-ion batteries (LIBs). Here, Cr2P2O7 with an in-situ formed carbon layer has been fabricated through a facile solid-state method and its storage performance in SIBs and LIBs has been reported first. The Cr2P2O7@C delivers 238 mA h g-1 and 717 mA h g-1 at 0.05 A g-1 in SIBs and LIBs, respectively. A capacity of 194 mA h g-1 is achieved in SIBs after 300 cycles at 0.1 A g-1 with a high capacity retention of 92.4%. When tested in LIBs, 351 mA h g-1 is maintained after 600 cycles at 0.1 A g-1. The carbon coating layer improves the conductivity and reduces the side reaction during the electrochemical process, and hence improves the rate performance and enhances the cyclic stability.

SUBMITTER: Wang S 

PROVIDER: S-EPMC7412520 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature

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Cr<sub>2</sub>P<sub>2</sub>O<sub>7</sub> as a Novel Anode Material for Sodium and Lithium Storage.

Wang Shuo S   Zhu Tianyuan T   Chen Fei F   Ding Xiang X   Hu Qiao Q   Liao Jiaying J   He Xiaodong X   Chen Chunhua C  

Materials (Basel, Switzerland) 20200714 14


The development of new appropriate anode material with low cost is still main issue for sodium-ion batteries (SIBs) and lithium-ion batteries (LIBs). Here, Cr<sub>2</sub>P<sub>2</sub>O<sub>7</sub> with an in-situ formed carbon layer has been fabricated through a facile solid-state method and its storage performance in SIBs and LIBs has been reported first. The Cr<sub>2</sub>P<sub>2</sub>O<sub>7</sub>@C delivers 238 mA h g<sup>-1</sup> and 717 mA h g<sup>-1</sup> at 0.05 A g<sup>-1</sup> in SIBs  ...[more]

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