Ontology highlight
ABSTRACT:
SUBMITTER: Jacovella U
PROVIDER: S-EPMC7416310 | biostudies-literature | 2020 Aug
REPOSITORIES: biostudies-literature
Jacovella Ugo U Carrascosa Eduardo E Buntine Jack T JT Ree Nicolai N Mikkelsen Kurt V KV Jevric Martyn M Moth-Poulsen Kasper K Bieske Evan J EJ
The journal of physical chemistry letters 20200715 15
Molecular photoswitches based on the norbornadiene-quadricylane (NBD-QC) couple have been proposed as key elements of molecular solar thermal energy storage schemes. To characterize the intrinsic properties of such systems, reversible isomerization of a charge-tagged NBD-QC carboxylate couple is investigated in a tandem ion mobility mass spectrometer, using light to induce intramolecular [2 + 2] cycloaddition of NBD carboxylate to form the QC carboxylate and driving the back reaction with molecu ...[more]