Ontology highlight
ABSTRACT:
SUBMITTER: Fontenelle CQ
PROVIDER: S-EPMC7418098 | biostudies-literature | 2020
REPOSITORIES: biostudies-literature
Fontenelle Clément Q CQ Thierry Thibault T Laporte Romain R Pfund Emmanuel E Lequeux Thierry T
Beilstein journal of organic chemistry 20200807
The selective ring-opening reaction of fluoroalkylidene-oxetanes was directed by the presence of the fluorine atom, enabling a two-step access to tetrasubstituted fluoroalkenes with excellent geometry control. Despite its small van der Waals radii electronic, rather than steric influences of the fluorine atom governed the ring-opening reaction with bromide ions, even in the presence of bulky substituents. ...[more]