Browse
Submit Data
Databases
API
Help

Dataset Information

8 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Surface slip on rotating graphene membrane enables the temporal selectivity that breaks the permeability-selectivity trade-off.

ABSTRACT: Membrane separation technology is dictated by the permeability-selectivity trade-off rule, because selectivity relies on membrane pore size being smaller than that of hydrated ions. We discovered a previously unknown mechanism that breaks the permeability-selectivity trade-off in using a rotating nanoporous graphene membrane with pores of 2 to 4 nanometers in diameter. The results show that the rotating membrane exhibits almost 100% salt rejection even when the pore size is larger than that of hydrated ions, and the surface slip at the liquid/graphene interface of rotating membrane enables concurrent ultra-selectivity and unprecedented high permeability. A novel concept of "temporal selectivity" is proposed to attribute the unconventional selectivity to the time difference between the ion's penetration time through the pore and the bypass time required for ion's sliding across the pore. The newly discovered temporal selectivity overcomes the limitation imposed by pore size and provokes a novel theory in designing high-performance membranes.

SUBMITTER: Zhang Z

PROVIDER: S-EPMC7438089 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Sensitivity-Selectivity Trade-Offs in Surface Ionization Gas Detection.

Project description:Surface ionization (SI) provides a simple, sensitive, and selective method for the detection of high-proton affinity substances, such as organic decay products, medical and illicit drugs as well as a range of other hazardous materials. Tests on different kinds of SI sensors showed that the sensitivity and selectivity of such devices is not only dependent on the stoichiometry and nanomorphology of the emitter materials, but also on the shape of the electrode configurations that are used to read out the SI signals. Whereas, in parallel-plate capacitor devices, different kinds of emitter materials exhibit a high level of amine-selectivity, MEMS (micro-electro-mechanical-systems) and NEMS (nanowire) versions of SI sensors employing the same kinds of emitter materials provide significantly higher sensitivity, however, at the expense of a reduced chemical selectivity. In this paper, it is argued that such sensitivity-selectivity trade-offs arise from unselective physical ionization phenomena that occur in the high-field regions immediately adjacent to the surfaces of sharply curved MEMS (NEMS) emitter and collector electrodes.

| S-EPMC6316693 | biostudies-other

Exploiting the Surface Properties of Graphene for Polymorph Selectivity.

Project description:Producing crystals of the desired form (polymorph) is currently a challenge as nucleation is yet to be fully understood. Templated crystallization is an efficient approach to achieve polymorph selectivity; however, it is still unclear how to design the template to achieve selective crystallization of specific polymorphs. More insights into the nanoscale interactions happening during nucleation are needed. In this work, we investigate crystallization of glycine using graphene, with different surface chemistry, as a template. We show that graphene induces the preferential crystallization of the metastable α-polymorph compared to the unstable β-form at the contact region of an evaporating droplet. Computer modeling indicates the presence of a small amount of oxidized moieties on graphene to be responsible for the increased stabilization of the α-form. In conclusion, our work shows that graphene could become an attractive material for polymorph selectivity and screening by exploiting its tunable surface chemistry.

| S-EPMC7605719 | biostudies-literature

Permeability and Selectivity of PPO/Graphene Composites as Mixed Matrix Membranes for CO₂ Capture and Gas Separation.

Project description:We fabricated novel composite (mixed matrix) membranes based on a permeable glassy polymer, Poly(2,6-dimethyl-1,4-phenylene oxide) (PPO), and variable loadings of few-layer graphene, to test their potential in gas separation and CO₂ capture applications. The permeability, selectivity and diffusivity of different gases as a function of graphene loading, from 0.3 to 15 wt %, was measured at 35 and 65 °C. Samples with small loadings of graphene show a higher permeability and He/CO₂ selectivity than pure PPO, due to a favorable effect of the nanofillers on the polymer morphology. Higher amounts of graphene lower the permeability of the polymer, due to the prevailing effect of increased tortuosity of the gas molecules in the membrane. Graphene also allows dramatically reducing the increase of permeability with temperature, acting as a "stabilizer" for the polymer matrix. Such effect reduces the temperature-induced loss of size-selectivity for He/N₂ and CO₂/N₂, and enhances the temperature-induced increase of selectivity for He/CO₂. The study confirms that, as observed in the case of other graphene-based mixed matrix glassy membranes, the optimal concentration of graphene in the polymer is below 1 wt %. Below such threshold, the morphology of the nanoscopic filler added in solution affects positively the glassy chains packing, enhancing permeability and selectivity, and improving the selectivity of the membrane at increasing temperatures. These results suggest that small additions of graphene to polymers can enhance their permselectivity and stabilize their properties.

| S-EPMC6414883 | biostudies-literature

High-temporal-resolution quasideterministic dynamics of granular stick-slip.

Project description:We report high-temporal-resolution observations of the spontaneous instability of model granular materials under isotropic and triaxial compression in fully drained conditions during laboratory tests representative of earthquakes. Unlike in natural granular materials, in the model granular materials, during the first stage of the tests, i.e., isotropic compression, a series of local collapses of various amplitudes occurs under random triggering cell pressures. During the second stage, i.e., shearing under triaxial compression, the model granular samples exhibit very large quasiperiodic stick-slip motions at random deviatoric triggering stresses. These motions are responsible for very large stress drops that are described by power laws and are accurate over more than 3 decades in logarithmic space. Then, we identify the quasideterministic nature of these stick-slip events, assuming that they are fully controlled by the cell pressure and solid fraction. Finally, we discuss the potential mechanisms that could explain these intriguing behaviors and the possible links with natural earthquakes.

| S-EPMC7858602 | biostudies-literature

Liquid water can slip on a hydrophilic surface.

Project description:Understanding and predicting the behavior of water, especially in contact with various surfaces, is a scientific challenge. Molecular-level understanding of hydrophobic effects and their macroscopic consequences, in particular, is critical to many applications. Macroscopically, a surface is classified as hydrophilic or hydrophobic depending on the contact angle formed by a water droplet. Because hydrophobic surfaces tend to cause water slip whereas hydrophilic ones do not, the former surfaces can yield self-cleaning garments and ice-repellent materials whereas the latter cannot. The results presented herein suggest that this dichotomy might be purely coincidental. Our simulation results demonstrate that hydrophilic surfaces can show features typically associated with hydrophobicity, namely liquid water slip. Further analysis provides details on the molecular mechanism responsible for this surprising result.

| S-EPMC3182716 | biostudies-literature

Ion selectivity of graphene nanopores.

Project description:As population growth continues to outpace development of water infrastructure in many countries, desalination (the removal of salts from seawater) at high energy efficiency will likely become a vital source of fresh water. Due to its atomic thinness combined with its mechanical strength, porous graphene may be particularly well-suited for electrodialysis desalination, in which ions are removed under an electric field via ion-selective pores. Here, we show that single graphene nanopores preferentially permit the passage of K(+) cations over Cl(-) anions with selectivity ratios of over 100 and conduct monovalent cations up to 5 times more rapidly than divalent cations. Surprisingly, the observed K(+)/Cl(-) selectivity persists in pores even as large as about 20 nm in diameter, suggesting that high throughput, highly selective graphene electrodialysis membranes can be fabricated without the need for subnanometer control over pore size.

| S-EPMC4844701 | biostudies-literature

Climbers' Perception of Hold Surface Properties: Roughness Versus Slip Resistance.

Project description:The more experienced a climber is, the more friction they can impart on a climbing hold surface. The aim of this research was to investigate how the properties of a hold's surface are perceived and how the perception relates to the amount of friction applied to the hold. The holds' surface properties are roughness/smoothness and grippiness/slippiness. Fourteen different surfaces with a wide range of property combinations were selected and placed on an instrumented climbing hold, mounted on a bouldering wall, and incorporated into a climbing route. Twenty-two climbers participated in the study. The ratio of friction to normal force (denoted friction coefficient or COF subsequently) was obtained from the sensor data, and the subjective ranking of the surface properties was provided by the participants. The average COF applied to the surfaces ranged from 0.53 (Teflon) to 0.84 (rubber). The surfaces with the lowest and highest grippiness and roughness ranking were Teflon and sandpaper, respectively. The correlation between roughness and COF was insignificant, whereas the correlation of grippiness and COF was significant. This applies to the 22 participants at the group level. At the individual level, 50% (11 climbers) of the participants did not show any correlations between surface properties and COF; eight climbers exhibited correlations between the combined grippiness and roughness (multiple regression) and COF, as well as grippiness and COF; only one climber out of the eight showed an additional correlation between roughness and COF. The results are interpreted in a way that climbers assess a hold's surface based on grippiness, and not on the roughness, and apply a COF to the hold that reflects the perception of grippiness.

| S-EPMC7088443 | biostudies-literature

Hedgehog signaling enables repair of ribosomal DNA double-strand breaks.

Project description:Ribosomal DNA (rDNA) consists of highly repeated sequences that are prone to incurring damage. Delays or failure of rDNA double-strand break (DSB) repair are deleterious, and can lead to rDNA transcriptional arrest, chromosomal translocations, genomic losses, and cell death. Here, we show that the zinc-finger transcription factor GLI1, a terminal effector of the Hedgehog (Hh) pathway, is required for the repair of rDNA DSBs. We found that GLI1 is activated in triple-negative breast cancer cells in response to ionizing radiation (IR) and localizes to rDNA sequences in response to both global DSBs generated by IR and site-specific DSBs in rDNA. Inhibiting GLI1 interferes with rDNA DSB repair and impacts RNA polymerase I activity and cell viability. Our findings tie Hh signaling to rDNA repair and this heretofore unknown function may be critically important in proliferating cancer cells.

| S-EPMC7544215 | biostudies-literature

Understanding water transport through graphene-based nanochannels via experimental control of slip length.

Project description:The water transport along graphene-based nanochannels has gained significant interest. However, experimental access to the influence of defects and impurities on transport poses a critical knowledge gap. Here, we investigate the water transport of cation intercalated graphene oxide membranes. The cations act as water-attracting impurities on the channel walls. Via water transport experiments, we show that the slip length of the nanochannels decay exponentially with the hydrated diameter of the intercalated cations, confirming that water transport is governed by the interaction between water molecules and the impurities on the channel wall. The exponential decay of slip length approximates non-slip conditions. This offers experimental support for the use of the Hagen-Poiseuille equation in graphene-based nanochannels, which was previously only confirmed by simulations. Our study gives valuable feedback to theoretical predictions of the water transport along graphene-based channels with water-attracting impurities.

| S-EPMC9519754 | biostudies-literature

The mixture effect on ionic selectivity and permeability of nanotubes.

Project description:Ion-selective nanotubes have great potential in applications such as ion separation, desalination, and power generation. However, their performance is often limited by the deteriorated selectivity in mixed salt solutions. To reveal the underlying mechanism of the mixture effect on ion transport through nanotubes, we perform molecular dynamics (MD) simulations on ion transport through carbon nanotubes (CNTs) and polymer nanopores with a pore diameter of ∼1 nm and a charge density of -1 e nm-2. Based on the simulation results, when a single salt solution is replaced by a mixed salt solution, the ionic selectivity drops as the permeability of higher permeable ions decreases much greater than that of lower permeable ions. This is because the adsorption of lower permeable ions on the inner surface of nanotubes blocks the ion flux and increases the entrance barrier to the nanotube, and the adsorption is significantly reduced in the mixed salt solution. Such a reduction results from the occupancy of higher permeable ions on the adsorption sites as they have a higher adsorption tendency albeit weaker adsorption compared with lower permeable ions. These studies will help design the next generation of nanostructures to circumvent the mixture effect and show high permeability and selectivity in real applications.

| S-EPMC9419827 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data