Dataset Information

Valorizing Plastic-Contaminated Waste Streams through the Catalytic Hydrothermal Processing of Polypropylene with Lignocellulose.

ABSTRACT: Food waste is a promising resource for the production of fuels and chemicals. However, increasing plastic contamination has a large impact on the efficiency of conversion for the more established biological routes such as anaerobic digestion or fermentation. Here, we assessed a novel route through the hydrothermal liquefaction (HTL) of a model waste (pistachio hulls) and polypropylene (PP). Pure pistachio hulls gave a biocrude yield of 34% (w/w), though this reduced to 16% (w/w) on the addition of 50% PP in the mixture. The crude composition was a complex blend of phenolics, alkanes, carboxylic acids, and other oxygenates, which did not change substantially on the addition of PP. Pure PP does not breakdown at all under HTL conditions (350 °C, 15% solids loading), and even with biomass, there is only a small synergistic effect resulting in a conversion of 19% PP. This conversion was enhanced through using typical HTL catalysts including Fe, FeSO4·7H2O, MgSO4·H2O, ZnSO4·7H2O, ZSM-5, aluminosilicate, Y-zeolite, and Na2CO3; the conversion of PP reached a maximum of 38% with the aluminosilicate, for example. However, the PP almost exclusively broke down into a solid-phase product, with no enhancement of the biocrude fraction. The mechanism was explored, and with the addition of the radical scavenger butylated hydroxytoluene (BHT), the conversion of plastic reduced substantially, demonstrating that radical formation is necessary. As a result, the plastic conversion was enhanced to over 50% through the addition of the co-solvent and hydrogen donor, formic acid, and the radical donor, hydrogen peroxide. The addition of formic acid also changed the crude composition, including more carboxylic acids and oxygenated species than the conversion of the biomass alone; however, the majority of the carbon distributed to the volatile organic gas fraction producing an array of short-chain volatile hydrocarbons, which potentially could be repolymerized as a polyolefin or combined with the biocrude for further processing. Catalytic HTL was therefore shown to be a promising method for the valorization of polyolefins with biomass under typical HTL conditions.

SUBMITTER: Hongthong S

PROVIDER: S-EPMC7439709 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature

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Valorizing Plastic-Contaminated Waste Streams through the Catalytic Hydrothermal Processing of Polypropylene with Lignocellulose.

Hongthong Sukanya S Leese Hannah S HS Chuck Christopher J CJ

ACS omega 20200807 32

Food waste is a promising resource for the production of fuels and chemicals. However, increasing plastic contamination has a large impact on the efficiency of conversion for the more established biological routes such as anaerobic digestion or fermentation. Here, we assessed a novel route through the hydrothermal liquefaction (HTL) of a model waste (pistachio hulls) and polypropylene (PP). Pure pistachio hulls gave a biocrude yield of 34% (w/w), though this reduced to 16% (w/w) on the addition ...[more]

PMID: 32832812

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Project description:The brewing industry generates a substantial amount of by-products rich in polyphenols, carbohydrates, sugars, sulfates, nitrogen compounds, organic carbon, and several elements, including chlorine, magnesium, and phosphorus. Although limited quantities of these by-products are used in fertilizers and composts, a large amount is discarded as waste. Therefore, it is crucial to identify different ways of valorizing the by-products. Research regarding the valorization of the brewery by-products is still in its nascent stage; therefore, it still has high potential. Herein, we report the valorization of the brewery by-product from the filtration stage of the brewing process (BW9) to synthesize silver nanocomposites as this waste has remained largely unexplored. The BW9 nanocomposites have been compared to those obtained from the brewery product B. The chemical composition analysis of BW9 and B revealed several organic moieties capable of reducing metal salts and capping the formed nanoparticles. Therefore, the brewery waste from stage 9 was valorized as a precursor and added to silver-based precursor at various temperatures (25, 50, and 80 °C) and for various time periods (10, 30, and 120 min) to synthesize silver nanocomposites. The nanocomposites obtained using BW9 were compared to those obtained using the main product of the brewing industry, beer (B). Synthesized nanocomposites composed of AgCl as a major phase and silver metal (Agmet) was incorporated in minor quantities. In addition, Ag3PO4 was also found in B nanocomposites in minor quantities (up to 34 wt.%). The surface morphology depicted globular nanoparticles with layered structures. Small ball-like aggregates on the layer representative of Ag3PO4 were observed in B nanocomposites. The surface of nanocomposites was capped with organic content and functional groups present in the brewery products. The nanocomposites demonstrated high antibacterial activity against Escherichia coli (E. coli), with BW9 nanocomposites exhibiting a higher activity than B nanocomposites.

Project description:BackgroundDelactosed whey permeate (DWP) is a side stream of whey processing, which often is discarded as waste, despite of its high residual content of lactose, typically 10-20%. Microbial fermentation is one of the most promising approaches for valorizing nutrient rich industrial waste streams, including those generated by the dairies. Here we present a novel microbial platform specifically designed to generate useful compounds from dairy waste. As a starting point we use Corynebacterium glutamicum, an important workhorse used for production of amino acids and other important compounds, which we have rewired and complemented with genes needed for lactose utilization. To demonstrate the potential of this novel platform we produce ethanol from lactose in DWP.ResultsFirst, we introduced the lacSZ operon from Streptococcus thermophilus, encoding a lactose transporter and a β-galactosidase, and achieved slow growth on lactose. The strain could metabolize the glucose moiety of lactose, and galactose accumulated in the medium. After complementing with the Leloir pathway (galMKTE) from Lactococcus lactis, co-metabolization of galactose and glucose was accomplished. To further improve the growth and increase the sugar utilization rate, the strain underwent adaptive evolution in lactose minimal medium for 100 generations. The outcome was strain JS95 that grew fast in lactose mineral medium. Nevertheless, JS95 still grew poorly in DWP. The growth and final biomass accumulation were greatly stimulated after supplementation with NH4+, Mn2+, Fe2+ and trace minerals. In only 24 h of cultivation, a high cell density (OD600 of 56.8 ± 1.3) was attained. To demonstrate the usefulness of the platform, we introduced a plasmid expressing pyruvate decarboxylase and alcohol dehydrogenase, and managed to channel the metabolic flux towards ethanol. Under oxygen-deprived conditions, non-growing suspended cells could convert 100 g/L lactose into 46.1 ± 1.4 g/L ethanol in DWP, a yield of 88% of the theoretical. The resting cells could be re-used at least three times, and the ethanol productivities obtained were 0.96 g/L/h, 2.2 g/L/h, and 1.6 g/L/h, respectively.ConclusionsAn efficient process for producing ethanol from DWP, based on C. glutamicum, was demonstrated. The results obtained clearly show a great potential for this newly developed platform for producing value-added chemicals from dairy waste.

Dataset Information

Valorizing Plastic-Contaminated Waste Streams through the Catalytic Hydrothermal Processing of Polypropylene with Lignocellulose.

Publications

Valorizing Plastic-Contaminated Waste Streams through the Catalytic Hydrothermal Processing of Polypropylene with Lignocellulose.

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