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Photoredox-catalyzed deoxyfluorination of activated alcohols with Selectfluor®.

ABSTRACT: Herein we disclose a deoxyfluorination of alcohols with an electrophilic fluorine source via visible-light photoredox catalysis. This radical-mediated C-F coupling is capable of fluorinating secondary and tertiary alcohols efficiently, complementing previously reported nucleophilic deoxyfluorination protocols.

SUBMITTER: Gonzalez-Esguevillas M 

PROVIDER: S-EPMC7441851 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature

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Photoredox-catalyzed deoxyfluorination of activated alcohols with Selectfluor<sup>®</sup>.

González-Esguevillas María M   Miró Javier J   Jeffrey Jenna L JL   MacMillan David W C DWC  

Tetrahedron 20190603 32

Herein we disclose a deoxyfluorination of alcohols with an electrophilic fluorine source via visible-light photoredox catalysis. This radical-mediated C-F coupling is capable of fluorinating secondary and tertiary alcohols efficiently, complementing previously reported nucleophilic deoxyfluorination protocols. ...[more]

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