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Experimental data of CaTiO3 photocatalyst for degradation of organic pollutants (Brilliant green dye) - Green synthesis, characterization and kinetic study.

ABSTRACT: The data presented here focuses on the physicochemical characterization of perovskite CaTiO3 nanoparticles (orthorhombic) as photocatalyts and the kinetic study of their photodegradation performance toward organic pollutant, i.e. brilliant green (BG) which is azo derivatives dye. The CaTiO3 nanoparticles was synthesized using chicken eggshell-derived CaCO3 and anatase TiO2 with molar ratio of (1:1), (1:3), (2:5), and (2:7). The physical and microstructural properties of CaTiO3 were characterized by X-ray diffractometer (XRD), scanning electron microscope (SEM), Fourier Transform Infrared (FTIR) and UV/vis spectrometer. The effect of initial dye concentration, catalyst composition, and catalyst dosage on the adsorption mechanism of dye on CaTiO3 was investigated in jacketed photoreactor under UV irradiation. The analysis reveals that BG molecules are efficiently chemisorbed, as indicated by pseudo first order kinetic, and degraded within 120?min. Considering the low-cost preparation process and high photocatalytic performance, the resultant CaTiO3 can further be used as an efficient photocatalyst for organic pollutant removal from aqueous and industrial wastewater.

SUBMITTER: Ernawati L

PROVIDER: S-EPMC7451799 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature

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Experimental data of CaTiO3 photocatalyst for degradation of organic pollutants (Brilliant green dye) - Green synthesis, characterization and kinetic study.

Ernawati Lusi L Wahyuono Ruri Agung RA Widiyandari Hendri H Risanti Doty Dewi DD Yusariarta Ade Wahyu AW Rebeka Sitompul Virginia V

Data in brief 20200731

The data presented here focuses on the physicochemical characterization of perovskite CaTiO3 nanoparticles (orthorhombic) as photocatalyts and the kinetic study of their photodegradation performance toward organic pollutant, i.e. brilliant green (BG) which is azo derivatives dye. The CaTiO3 nanoparticles was synthesized using chicken eggshell-derived CaCO3 and anatase TiO2 with molar ratio of (1:1), (1:3), (2:5), and (2:7). The physical and microstruct ...[more]

PMID: 32904179

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Project description:In this work, we report the facile, environmentally friendly, room-temperature (RT) synthesis of porous CuO nanosheets and their application as a photocatalyst to degrade an organic pollutant/food dye using NaBH4 as the reducing agent in an aqueous medium. Ultrahigh-resolution field effect scanning electron microscopy images of CuO displayed a broken nanosheet-like (a length of ∼160 nm, a width of ∼65 nm) morphology, and the lattice strain was estimated to be ∼1.24 × 10-3 using the Williamson-Hall analysis of X-ray diffraction plots. Owing to the strong quantum size confinement effect, CuO nanosheets resulted in an optical energy band gap of ∼1.92 eV, measured using Tauc plots of the ultraviolet-visible (UV-vis) spectrum, resulting in excellent photocatalytic efficiency. The RT synthesized CuO catalyst showed a high Brunauer-Emmet-Teller surface area of 30.88 ± 0.2313 m2/g (a correlation coefficient of 0.99972) with an average Barrett-Joyner-Halenda pore size of ∼20.385 nm. The obtained porous CuO nanosheets exhibited a high crystallinity of 73.5% with a crystallite size of ∼12 nm and was applied as an efficient photocatalyst for degradation of the organic pollutant/food dye, Allura Red AC (AR) dye, as monitored by UV-vis spectrophotometric analysis and evidenced by a color change from red to colorless. From UV-vis spectra, CuO nanosheets exhibited an efficient and ultrafast photocatalytic degradation efficiency of ∼96.99% for the AR dye in an aqueous medium within 6 min at RT. According to the Langmuir-Hinshelwood model, photodegradation reaction kinetics followed a pseudo-first-order reaction with a rate constant of k = 0.524 min-1 and a half-life (t 1/2) of 2.5 min for AR dye degradation in the aqueous medium. The CuO nanosheets showed an outstanding recycling ability for AR degradation and would be highly favorable and an efficient catalyst due to the synergistic effect of high adsorption capability and photodegradation of the food dye.

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Experimental data of CaTiO3 photocatalyst for degradation of organic pollutants (Brilliant green dye) - Green synthesis, characterization and kinetic study.

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Experimental data of CaTiO<sub>3</sub> photocatalyst for degradation of organic pollutants (Brilliant green dye) - Green synthesis, characterization and kinetic study.

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