Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Charge density waves and degenerate modes in exfoliated monolayer 2H-TaS2.

ABSTRACT: Charge density waves spontaneously breaking lattice symmetry through periodic lattice distortion, and electron-electron and electron-phonon inter-actions, can lead to a new type of electronic band structure. Bulk 2H-TaS2 is an archetypal transition metal dichalcogenide supporting charge density waves with a phase transition at 75?K. Here, it is shown that charge density waves can exist in exfoliated monolayer 2H-TaS2 and the transition temperature can reach 140?K, which is much higher than that in the bulk. The degenerate breathing and wiggle modes of 2H-TaS2 originating from the periodic lattice distortion are probed by optical methods. The results open an avenue to investigating charge density wave phases in two-dimensional transition metal dichalcogenides and will be helpful for understanding and designing devices based on charge density waves.

SUBMITTER: Zhang D

PROVIDER: S-EPMC7467171 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Charge density waves and degenerate modes in exfoliated monolayer 2H-TaS2.

Zhang Duan D Wu Yecun Y Su Yu-Hsin YH Hsu Ming-Chien MC Ó Coileáin Cormac C Cho Jiung J Choi Miri M Chun Byong Sun BS Guo Yao Y Chang Ching-Ray CR Wu Han-Chun HC

IUCrJ 20200825 Pt 5

Charge density waves spontaneously breaking lattice symmetry through periodic lattice distortion, and electron-electron and electron-phonon inter-actions, can lead to a new type of electronic band structure. Bulk 2H-TaS2 is an archetypal transition metal dichalcogenide supporting charge density waves with a phase transition at 75 K. Here, it is shown that charge density waves can exist in exfoliated monolayer 2H-TaS2 and the transition temperature can reach 140 K, which is ...[more]

PMID: 32939283

Similar Datasets

Atomic lattice disorder in charge-density-wave phases of exfoliated dichalcogenides (1T-TaS2).

Project description:Charge-density waves (CDWs) and their concomitant periodic lattice distortions (PLDs) govern the electronic properties in several layered transition-metal dichalcogenides. In particular, 1T-TaS2 undergoes a metal-to-insulator phase transition as the PLD becomes commensurate with the crystal lattice. Here we directly image PLDs of the nearly commensurate (NC) and commensurate (C) phases in thin, exfoliated 1T-TaS2 using atomic resolution scanning transmission electron microscopy at room and cryogenic temperature. At low temperatures, we observe commensurate PLD superstructures, suggesting ordering of the CDWs both in- and out-of-plane. In addition, we discover stacking transitions in the atomic lattice that occur via one-bond-length shifts. Interestingly, the NC PLDs exist inside both the stacking domains and their boundaries. Transitions in stacking order are expected to create fractional shifts in the CDW between layers and may be another route to manipulate electronic phases in layered dichalcogenides.

| S-EPMC5068312 | biostudies-literature

Structure and control of charge density waves in two-dimensional 1T-TaS2.

Project description:The layered transition metal dichalcogenides host a rich collection of charge density wave phases in which both the conduction electrons and the atomic structure display translational symmetry breaking. Manipulating these complex states by purely electronic methods has been a long-sought scientific and technological goal. Here, we show how this can be achieved in 1T-TaS2 in the 2D limit. We first demonstrate that the intrinsic properties of atomically thin flakes are preserved by encapsulation with hexagonal boron nitride in inert atmosphere. We use this facile assembly method together with transmission electron microscopy and transport measurements to probe the nature of the 2D state and show that its conductance is dominated by discommensurations. The discommensuration structure can be precisely tuned in few-layer samples by an in-plane electric current, allowing continuous electrical control over the discommensuration-melting transition in 2D.

| S-EPMC4679066 | biostudies-other

Fingerprints of magnetoinduced charge density waves in monolayer graphene beyond half filling.

Project description:A charge density wave is a condensate of fermions, whose charge density shows a long-range periodic modulation. Such charge density wave can be principally described as a macroscopic quantum state and is known to occur by various formation mechanisms. These are the lattice deforming Peierls transition, the directional, fermionic wave vector orientation prone Fermi surface nesting or the generic charge ordering, which in contrast is associated solely with the undirected effective Coulomb interaction between fermions. In two-dimensional Dirac/Weyl-like systems, the existence of charge density waves is only theoretically predicted within the ultralow energy regime at half filling. Taking graphene as host of two-dimensional fermions described by a Dirac/Weyl Hamiltonian, we tuned indirectly the effective mutual Coulomb interaction between fermions through adsorption of tetracyanoquinodimethane on top in the low coverage limit. We thereby achieved the development of a novel, low-dimensional dissipative charge density wave of Weyl-like fermions, even beyond half filling with additional magneto-induced localization and quantization. This charge density wave appears both, in the electron and the hole spectrum.

| S-EPMC9755137 | biostudies-literature

Patterns and driving forces of dimensionality-dependent charge density waves in 2H-type transition metal dichalcogenides.

Project description:Charge density wave (CDW) is a startling quantum phenomenon, distorting a metallic lattice into an insulating state with a periodically modulated charge distribution. Astonishingly, such modulations appear in various patterns even within the same family of materials. Moreover, this phenomenon features a puzzling diversity in its dimensional evolution. Here, we propose a general framework, unifying distinct trends of CDW ordering in an isoelectronic group of materials, 2H-MX2 (M = Nb, Ta and X = S, Se). We show that while NbSe2 exhibits a strongly enhanced CDW order in two dimensions, TaSe2 and TaS2 behave oppositely, with CDW being absent in NbS2 entirely. Such a disparity is demonstrated to arise from a competition of ionic charge transfer, electron-phonon coupling, and electron correlation. Despite its simplicity, our approach can, in principle, explain dimensional dependence of CDW in any material, thereby shedding new light on this intriguing quantum phenomenon and its underlying mechanisms.

| S-EPMC7229047 | biostudies-literature

In operando cryo-STEM of pulse-induced charge density wave switching in TaS2

Project description: Not available

| S-EPMC10713631 | biostudies-literature

Controlling charge-density-wave states in nano-thick crystals of 1T-TaS2.

Project description:Two-dimensional crystals, especially graphene and transition metal dichalcogenides (TMDs), are attracting growing interests because they provide an ideal platform for novel and unconventional electronic band structures derived by thinning. The thinning may also affect collective phenomena of electrons in interacting electron systems and can lead to exotic states beyond the simple band picture. Here, we report the systematic control of charge-density-wave (CDW) transitions by changing thickness, cooling rate and gate voltage in nano-thick crystals of 1T-type tantalum disulfide (1T-TaS2). Particularly the clear cooling rate dependence, which has never been observed in bulk crystals, revealed the nearly-commensurate CDW state in nano-thick crystals is a super-cooled state. The present results demonstrate that, in the two-dimensional crystals with nanometer thickness, the first-order phase transitions are susceptible to various perturbations, suggestive of potential functions of electronic phase control.

| S-EPMC4252899 | biostudies-other

Charge Density Waves in Electron-Doped Molybdenum Disulfide.

Project description:We present the discovery of a charge density wave (CDW) ground state in heavily electron-doped molybdenum disulfide (MoS2). This is the first observation of a CDW in any d2 (column 6) transition metal dichalcogenide (TMD). The band structure of MoS2 is distinct from the d0 and d1 TMDs in which CDWs have been previously observed, facilitating new insight into CDW formation. We demonstrate a metal-insulator transition at 85 K, a 25 meV gap at the Fermi level, and two distinct CDW modulations, (2√3 × 2√3) R30° and 2 × 2, attributable to Fermi surface nesting (FSN) and electron-phonon coupling (EPC), respectively. This simultaneous exhibition of FSN and EPC CDW modulations is unique among observations of CDW ground states, and we discuss this in the context of band folding. Our observations provide a route toward the resolution of controversies surrounding the origin of CDW modulations in TMDs.

| S-EPMC8397392 | biostudies-literature

Classification of charge density waves based on their nature.

Project description:The concept of a charge density wave (CDW) permeates much of condensed matter physics and chemistry. CDWs have their origin rooted in the instability of a one-dimensional system described by Peierls. The extension of this concept to reduced dimensional systems has led to the concept of Fermi surface nesting (FSN), which dictates the wave vector [Formula: see text] of the CDW and the corresponding lattice distortion. The idea is that segments of the Fermi contours are connected by [Formula: see text], resulting in the effective screening of phonons inducing Kohn anomalies in their dispersion at [Formula: see text], driving a lattice restructuring at low temperatures. There is growing theoretical and experimental evidence that this picture fails in many real systems and in fact it is the momentum dependence of the electron-phonon coupling (EPC) matrix element that determines the characteristic of the CDW phase. Based on the published results for the prototypical CDW system 2H-NbSe2, we show how well the [Formula: see text]-dependent EPC matrix element, but not the FSN, can describe the origin of the CDW. We further demonstrate a procedure of combing electronic band and phonon measurements to extract the EPC matrix element, allowing the electronic states involved in the EPC to be identified. Thus, we show that a large EPC does not necessarily induce the CDW phase, with Bi2Sr2CaCu2O8+δ as the example, and the charge-ordered phenomena observed in various cuprates are not driven by FSN or EPC. To experimentally resolve the microscopic picture of EPC will lead to a fundamental change in the way we think about, write about, and classify charge density waves.

| S-EPMC4345626 | biostudies-literature

Chirality locking charge density waves in a chiral crystal.

Project description:In Weyl semimetals, charge density wave (CDW) order can spontaneously break the chiral symmetry, gap out the Weyl nodes, and drive the material into the axion insulating phase. Investigations have however been limited since CDWs are rarely seen in Weyl semimetals. Here, using scanning tunneling microscopy/spectroscopy (STM/S), we report the discovery of a novel unidirectional CDW order on the (001) surface of chiral crystal CoSi - a unique Weyl semimetal with unconventional chiral fermions. The CDW is incommensurate with both lattice momentum and crystalline symmetry directions, and exhibits an intra unit cell π phase shift in the layer stacking direction. The tunneling spectrum shows a particle-hole asymmetric V-shaped energy gap around the Fermi level that modulates spatially with the CDW wave vector. Combined with first-principle calculations, we identify that the CDW is locked to the crystal chirality and is related by a mirror reflection between the two enantiomers of the chiral crystal. Our findings reveal a novel correlated topological quantum state in chiral CoSi crystals and raise the potential for exploring the unprecedented physical behaviors of unconventional chiral fermions.

| S-EPMC9133074 | biostudies-literature

Condensation of preformed charge density waves in kagome metals.

Project description:Charge density wave (CDW) is a spontaneous spatial modulation of charges in solids whose general microscopic descriptions are yet to be completed. Kagome metals of AV3Sb5 (A = K, Rb, Cs) provide a chance to realize CDW intertwined with dimensional effects as well as their special lattice. Here, based on a state-of-the-art molecular dynamics simulation, we propose that their phase transition to CDW is a condensation process of incoherently preformed charge orders. Owing to unavoidable degeneracy in stacking charge orders, phases of preformed orders on each layer are shown to fluctuate between a limited number of states with quite slower frequencies than typical phonon vibrations until reaching their freezing temperature. As the size of interfacial alkali atom increases, the fluctuations are shown to counterbalance the condensation of orderings, resulting in a maximized transition temperature for RbV3Sb5. Our results resolve controversial observations on their CDWs, highlighting a crucial role of their interlayer interactions.

| S-EPMC10640577 | biostudies-literature