Ontology highlight
ABSTRACT:
SUBMITTER: Berger F
PROVIDER: S-EPMC7467811 | biostudies-literature | 2020 Jul
REPOSITORIES: biostudies-literature
Berger Florian F Alvarez Eva Maria EM Frank Nils N Bohdan Kostiantyn K Kondratiuk Mykhailo M Torkowski Luca L Engl Pascal S PS Barletta Joana J Ritter Tobias T
Organic letters 20200708 14
We report a nucleophilic substitution reaction of five-membered hetarylsulfonium salts that results in a change of the substitution pattern on the arene. The products of these <i>cine</i>-substitutions are hard to access synthetically otherwise. The sulfonium salts that serve as starting materials are generated by a highly site-selective C-H functionalization reaction. ...[more]