Unknown

Dataset Information

0

Structures and Properties of trans-1,3,3,3-Tetrafluoro- propene (HFO-1234ze) and 2,3,3,3-Tetrafluoropropene (HFO-1234yf) Refrigerants.

ABSTRACT: The refrigerant trans-1,3,3,3-tetrafluoropropene (HFO-1234ze) is used as a replacement for former cooling agents that have been phased-out due to their global warming potential or ozone depleting potential. Although it is used on a large scale, only a few vibrational data and no structural data of HFO-1234ze are known. We report structure determinations based on low-temperature single-crystal X-ray diffraction data as well as gas-phase diffraction data of HFO-1234ze and HFO-1234yf (2,3,3,3-tetrafluoropropene). Furthermore, vibrational spectra of HFO-1234ze in all phases are described. The results are discussed together with quantum-chemical calculations on the PBE0/cc-pVTZ level of theory. Combustion experiments of HFO-1234ze show carbonyl difluoride, carbon dioxide and hydrogen fluoride to be the main combustion products.

SUBMITTER: Schwabedissen J 

PROVIDER: S-EPMC7469860 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Structures and Properties of <i>trans</i>-1,3,3,3-Tetrafluoro- propene (HFO-1234ze) and 2,3,3,3-Tetrafluoropropene (HFO-1234yf) Refrigerants.

Schwabedissen Jan J   Glodde Timo T   Vishnevskiy Yury V YV   Stammler Hans-Georg HG   Flierl Lukas L   Kornath Andreas J AJ   Mitzel Norbert W NW  

ChemistryOpen 20200903 9

The refrigerant <i>trans-</i>1,3,3,3-tetrafluoropropene (HFO-1234ze) is used as a replacement for former cooling agents that have been phased-out due to their global warming potential or ozone depleting potential. Although it is used on a large scale, only a few vibrational data and no structural data of HFO-1234ze are known. We report structure determinations based on low-temperature single-crystal X-ray diffraction data as well as gas-phase diffraction data of HFO-1234ze and HFO-1234yf (2,3,3,  ...[more]

Similar Datasets

Unknown Thermal Conductivity of Binary Mixtures of 1,1,1,2-Tetrafluoroethane(R-134a), 2,3,3,3-Tetrafluoropropene (R-1234yf), and trans-1,3,3,3-Tetrafluoropropene (R-1234ze(E)) Refrigerants
| S-EPMC10092145 | biostudies-literature
Unknown Speed of Sound Measurements of Binary Mixtures of 1,1,1,2-Tetrafluoroethane (R-134a), 2,3,3,3-Tetrafluoropropene (R-1234yf), and <i>trans</i>-1,3,3,3-Tetrafluoropropene (R-1234ze(E)) Refrigerants.
| S-EPMC10092117 | biostudies-literature
Unknown Bubble Point Measurements of Three Binary Mixtures of Refrigerants: R-32/1234yf, R-32/1234ze(E) and R-1132a/1234yf.
| S-EPMC10020978 | biostudies-literature
Unknown Accumulation and phytotoxicity of perfluorooctanoic acid and 2,3,3,3-tetrafluoro-2-(heptafluoropropoxy)propanoate in Arabidopsis thaliana and Nicotiana benthamiana.
| S-EPMC7307574 | biostudies-literature
Unknown Methods based on a semi-empirical model for simulating scroll compressors with HFC and HFO refrigerants.
| S-EPMC10446056 | biostudies-literature
Unknown Molecular simulation data for the vapor-liquid phase equilibria of binary mixtures of HFO-1123 with R-32, R-1234yf, R-1234ze(E), R-134a and CO<sub>2</sub> and their modelling by the PCP-SAFT equation of state.
| S-EPMC6661389 | biostudies-literature
Unknown Correlations for the Viscosity of 2,3,3,3-Tetrafluoroprop-1-ene (R1234yf) and <i>trans</i>-1,3,3,3-Tetrafluoropropene (R1234ze(E)).
| S-EPMC5103321 | biostudies-literature
Unknown Transition Metal Coordination Polymers with Trans-1,4-Cyclohexanedicarboxylate: Acidity-Controlled Synthesis, Structures and Properties.
| S-EPMC7014088 | biostudies-literature
Unknown (R)Evolution of Refrigerants.
| S-EPMC8739722 | biostudies-literature
Unknown An eccentric rod-like linear connection of two heterocycles: synthesis of pyridine trans-tetrafluoro-?6-sulfanyl triazoles.
| S-EPMC5994873 | biostudies-other