Efficient occlusion of oil droplets within calcite crystals.

ABSTRACT: It is well known that oil and water do not mix. Similarly, the incorporation of oil droplets within inorganic crystals is highly counter-intuitive because there is a large difference in surface energy for these two components. Nevertheless, herein we demonstrate the efficient occlusion of ?250-500 nm oil droplets within 20-40 ?m calcite crystals. These droplets are stabilized using various amphiphilic poly(methacrylic acid)-poly(n-alkyl methacrylate) diblock copolymer emulsifiers. Both copolymer concentration and diblock compositions affect the extent of occlusion, with optimized conditions producing calcite crystals containing up to 11% oil by mass. Moreover, compressive forces exerted by the growing crystals cause significant deformation of the oil droplets during occlusion. In principle, this protocol enables the incorporation of water-insoluble dyes or hydrophobic nanoparticles within calcite, which is a cheap, naturally-occurring and environmentally-benign mineral. The single crystal nature of this host lattice ensures efficient retention of such guests, while lowering the solution pH leads to triggered release via acid dissolution.

SUBMITTER: Ning Y 

PROVIDER: S-EPMC7472555 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature