Ontology highlight
ABSTRACT:
SUBMITTER: Su B
PROVIDER: S-EPMC7484944 | biostudies-literature | 2018 Aug
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20180713 32
peri-Disubstituted naphthalenes exhibit interesting physical properties and unique chemical reactivity, due to the parallel arrangement of the bonds to the two peri-disposed substituents. Regioselective installation of a functional group at the position peri to 1-substituted naphthalenes is challenging due to the steric interaction between the existing substituent and the position at which the second one would be installed. We report an iridium-catalyzed borylation of the C-H bond peri to a sily ...[more]