Ontology highlight
ABSTRACT:
SUBMITTER: Ghana P
PROVIDER: S-EPMC7496515 | biostudies-literature | 2020 Aug
REPOSITORIES: biostudies-literature
Ghana Priyabrata P Hoffmann Alexander A Spaniol Thomas P TP Okuda Jun J
Chemistry (Weinheim an der Bergstrasse, Germany) 20200713 45
Alkali metal naphthalenide or anthracenide reacted with scandium(III) anilides [Sc(X){N(tBu)Xy}<sub>2</sub> (thf)] (X=N(tBu)Xy (1); X=Cl (2); Xy=C<sub>6</sub> H<sub>3</sub> -3,5-Me<sub>2</sub> ) to give scandium complexes [M(thf)<sub>n</sub> ][Sc{N(tBu)Xy}<sub>2</sub> (RA)] (M=Li-K; n=1-6; RA=C<sub>10</sub> H<sub>8</sub> <sup>2-</sup> (3-Naph-K) and C<sub>14</sub> H<sub>10</sub> <sup>2-</sup> (3-Anth-M)) containing a reduced arene ligand. Single-crystal X-ray diffraction revealed the scandium(II ...[more]